Some Mechanistic Evidence for an Oxygen Transfer Reaction Accompanied by the Redox-Induced Nitrito-Nitro Linkage Isomerization of Ruthenium Complex Having Nitrosyl, <i>cis</i>-[Ru(NO)(X)(bpy)2]2+ (X = ONO, NO2)

DOI PDF 28 References
  • Dai Ooyama
    Department of Chemistry, Faculty of Science and Engineering, Sophia University
  • Hirotaka Nagao
    Department of Chemistry, Faculty of Science and Engineering, Sophia University
  • Noriharu Nagao
    Department of Chemistry, Faculty of Science and Engineering, Sophia University
  • F Scott Howell
    Department of Chemistry, Faculty of Science and Engineering, Sophia University
  • Masao Mukaida
    Department of Chemistry, Faculty of Science and Engineering, Sophia University

Search this article

Abstract

<jats:title>Abstract</jats:title> <jats:p>An oxygen transfer between the NO and the ONO ligands occurs in cis-[Ru(NO)(ONO)(bpy)2]2+ when the complex undergoes a redox-induced nitrito-to-nitro linkage isomerization. Such an oxygen transfer does not occur in a themally-induced linkage isomerization reported previously.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 25 (9), 759-760, 1996-09-01

    Oxford University Press (OUP)

References(28)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top