An Efficient Method for Catalytic and Stereoselective Glycosylation with Thioglycosides Promoted by Trityl Tetrakis(pentafluorophenyl)borate and Sodium Periodate

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  • Hiromi Uchiro
    Department of Applied Chemistry, Faculty of Science, Science University of TokyoKagurazaka, Shinjuku-ku, Tokyo
  • Teruaki Mukaiyama
    Department of Applied Chemistry, Faculty of Science, Science University of TokyoKagurazaka, Shinjuku-ku, Tokyo

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Abstract

<jats:title>Abstract</jats:title> <jats:p>A new and efficient method for catalytic stereoselecive synthesis of several glycosides from thioglycosides is successfully performed by the combined use of trityl salt and sodium periodate. Several β-d-gluco- and galactopyranosides are prepared in good yields with high stereoselectivities.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (2), 121-122, 1997-02-01

    Oxford University Press (OUP)

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