Iridium-Catalyzed Redistribution of Hydrodisilanes <i>via</i> a Silyl(silylene)iridium(III) Complex: Synthesis of a Donor-Stabilized Silyl(silylene)iridium(III) Complex

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  • Masaaki Okazaki
    Department of Chemistry, Graduate School of Science, Tohoku UniversitySendai
  • Hiromi Tobita
    Department of Chemistry, Graduate School of Science, Tohoku UniversitySendai
  • Hiroshi Ogino
    Department of Chemistry, Graduate School of Science, Tohoku UniversitySendai

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Thermolysis of HMePhSiSiMe3 in the presence of a catalytic amount of Ir{η2-Me2Si(CH2)2PPh2} (PMe3)3 resulted in the redistribution of substituents to give its isomer HMe2SiSiMe2Ph. We propose the mechanism involving the 1,3-Me-shift on a silyl(silylene) complex, which was trapped as a donor-stabilized silyl(silylene)iridium(III) complex.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (5), 437-438, 1997-05-01

    Oxford University Press (OUP)

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