Generation of 1,3-Selenaza-1,3-butadienes by Thermal Cycloreversion of 2,4,6-Trisubstituted 6<i>H</i>-1,3,5-Oxaselenazines

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  • Kazuaki Shimada
    Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate UniversityMorioka, Iwate
  • Kei Aikawa
    Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate UniversityMorioka, Iwate
  • Takuji Fujita
    Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate UniversityMorioka, Iwate
  • Shigenobu Aoyagi
    Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate UniversityMorioka, Iwate
  • Yuji Takikawa
    Department of Applied Chemistry and Molecular Science, Faculty of Engineering, Iwate UniversityMorioka, Iwate
  • Chizuko Kabuto
    Department of Chemistry, Faculty of Science, Tohoku UniversitySendai, Miyagi

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Abstract

<jats:title>Abstract</jats:title> <jats:p>1,3-Selenaza-1,3-butadienes were generated by thermal cycloreversion of 6H-1,3,5-oxaselenazines, and were trapped with dienophiles or nucleophiles to give the corresponding [4+2] cycloadducts or 1,4-adducts, respectively.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (8), 701-702, 1997-08-01

    Oxford University Press (OUP)

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