Synthesis of Solid Solutions in a System of LiCoO2-Li2MnO3 for Cathode Materials of Secondary Lithium Batteries

  • Koichi Numata
    Battery Materials Research Laboratory, Mitsui Mining and Smelting Co., Ltd.Takehara, Hiroshima
  • Chie Sakaki
    Department of Applied Chemistry, Faculty of Engineering, Hiroshima UniversityHigashi-Hiroshima, Hiroshima
  • Shoji Yamanaka
    Department of Applied Chemistry, Faculty of Engineering, Hiroshima UniversityHigashi-Hiroshima, Hiroshima

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Lithium-manganese-cobalt oxide, Li(Lix/3MN2x/3Co1−x)O2 (0 ≤ x ≤ 1) was prepared as a solid solution between the two kinds of layer structured end members, LiCoO2 and Li2MnO3. Excess lithium carbonate or lithium hydroxide should be added to the mixture on calcination at 900 - 1000 °C to obtain the solid solutions. The resulting layer structured solid solutions can be used as a cathode material for secondary lithium batteries.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (8), 725-726, 1997-08-01

    Oxford University Press (OUP)

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