Lanthanoid Complexes of Azobenzene and Benzo[<i>c</i>]cinnoline Derived from Metallic Lanthanoids: Crystal Structures of Binuclear [SmI(thf)3(<i>μ</i>-<i>η</i>2:<i>η</i>2-<i>trans</i>-PhNNPh)SmI(thf)3] and Mononuclear [Yb(benzo[<i>c</i>]cinnoline)3(thf)2]

DOI PDF 1 Citations 23 References
  • Yuushou Nakayama
    Department of Macromolecular Science, Graduate School of Science, Osaka UniversityToyonaka, Osaka
  • Akira Nakamura
    Department of Macromolecular Science, Graduate School of Science, Osaka UniversityToyonaka, Osaka
  • Kazushi Mashima
    Department of Chemistry, Graduate School of Engineering Science, Osaka UniversityToyonaka, Osaka

Search this article

Abstract

<jats:title>Abstract</jats:title> <jats:p>A binuclear samarium complex of azobenzene, [SmI(thf)3(μ-η2:η2-trans-PhNNPh)2SmI(thf)3], prepared by treating metallic samarium with azobenzene in the presence of iodine was characterized crystallographically. Reaction of metallic ytterbium with benzo[c]cinnoline, a cis-azo compound, gave Yb(bc)3(thf)2 (bc = benzo[c]cinnoline) that is monomeric and adopts distorted dodecahedral geometry, determined by X-ray analysis.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (8), 803-804, 1997-08-01

    Oxford University Press (OUP)

Citations (1)*help

See more

References(23)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top