Synthesis and Crystal Structure of the Tetranuclear Copper(I) Complex [Cu4I4(MPTQ)2] with a <i>N</i>,<i>S</i>,<i>N</i>′-Tridentate Ligand(MPTQ = 8-((2-Pyridylmethyl)thio)quinoline)

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  • Cheng-Yong Su
    Institute of Physical Chemistry, School of Chemistry and Chemical Engineering, Zhongshan UniversityGuangzhou 510275 , China
  • Bei-Sheng Kang
    Institute of Physical Chemistry, School of Chemistry and Chemical Engineering, Zhongshan UniversityGuangzhou 510275 , China
  • Jie Sun
    Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of SciencesShanghai 200032 , China

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Copper(I) iodide reacts with 8-((2-pyridylmethyl)thio)quinoline (MPTQ) to give the tetranuclear cluster complex [Cu4I4(MPTQ)2] which has been structurally characterized, showing that the Cu4I4 core exists in a distorted chair-like structure with four copper atoms forming parallelogram which is bridged by iodine atoms on each short sides, by S, N-MPTQ on each long sides and with two additional iodine atoms face-bridging sets of three copper atoms on opposite sides of the parallelogram.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (8), 821-822, 1997-08-01

    Oxford University Press (OUP)

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