Asymmetric Transfer Hydrogenation Catalyzed by Diamine - Iridium(I) Complexes

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  • Shin-ichi Inoue
    Department of Applied Chemistry, Aichi Institute of Technology1247 Yachigusa, Yagusa-cho, Toyota, Aichi
  • Kenji Nomura
    Department of Applied Chemistry, Aichi Institute of Technology1247 Yachigusa, Yagusa-cho, Toyota, Aichi
  • Shohei Hashiguchi
    ERATO Molecular Catalysis Project, Research Development Corporation of Japan1247 Yachigusa, Yagusa-cho, Toyota, Aichi
  • Ryoji Noyori
    ERATO Molecular Catalysis Project, Research Development Corporation of Japan1247 Yachigusa, Yagusa-cho, Toyota, Aichi
  • Yasuji Izawa
    Department of Applied Chemistry, Aichi Institute of Technology1247 Yachigusa, Yagusa-cho, Toyota, Aichi

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Asymmetric transfer hydrogenation of a range of aromatic ketones in 2-propanol was carried out by using the iridium(I) complexes, prepared from [IrCl(cod)]2 and a variety of chiral diamine ligands derived from α-amino acids. Good catalytic activity and enantioselectivity were observed in the presence of KOH at room temperature.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 26 (9), 957-958, 1997-09-01

    Oxford University Press (OUP)

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