Electrochemical Deacetylation of 1,3-Dicarbonyl Compounds

• Kazuo Fujimoto

  Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University

• Hirofumi Maekawa

  Osaka Municipal Technical Research Institute

• Yoshiharu Matsubara

  Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University

• Ikuzo Nishiguchi

  Osaka Municipal Technical Research Institute

Abstract

Mild deacetylation of 1,3-dicarbonyl compounds was achieved by halonium-ion mediated electrolysis. In this reaction, the supporting electrolyte including sodium halide NaX (X = Cl or Br) was essential since the reaction proceeded through substitution by a halonium ion, generated electrochemically at anode, on active methine carbons followed by base-catalyzed deacetylation, and was terminated by reductlve dehalogenation of the formed α-halo carbonyl compounds at cathode.

Journal

• Chemistry Letters

  Chemistry Letters 25 (2), 143-144, 1996-02-01

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360846644039291008
• NII Article ID: 10003738688
• NII Book ID: AA00603318
• DOI: 10.1246/cl.1996.143
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/25/2/143/56069832/cl.1996.143.pdf
• Data Source:
  • Crossref
  • CiNii Articles