Selective Isomerization of 2-Allylphenol to (<i>Z</i>)-2-Propenylphenol Catalyzed by Ru(cod)(cot)/PEt3

• Takehiro Sato

  Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology2-24-16 Nakacho, Koganei, Tokyo

• Nobuyuki Komine

  Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology2-24-16 Nakacho, Koganei, Tokyo

• Masafumi Hirano

  Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology2-24-16 Nakacho, Koganei, Tokyo

• Sanshiro Komiya

  Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology2-24-16 Nakacho, Koganei, Tokyo

Abstract

Ru(cod)(cot) (cod = cycloocta-1,5-diene, cot = cycloocta-1,3,5-triene) catalyzes selective isomerization of 2-allylphenol to (Z)-2-propenylphenol in the presence of triethylphosphine with high yield (94%) and (Z)-selectivity (97%).

Journal

• Chemistry Letters

  Chemistry Letters 28 (5), 441-442, 1999-05-01

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360846644039801216
• NII Article ID: 10004341746
• NII Book ID: AA00603318
• DOI: 10.1246/cl.1999.441
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/28/5/441/56076314/cl.1999.441.pdf
• Data Source:
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  • CiNii Articles