Chirality-dependent Gel Formation from Sugars and Boronic-acid-appended Chiral Amphiphiles

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  • Taro Kimura
    Department of Chemical Science & Technology, Faculty of Engineering, Kyushu University
  • Seiji Shinkai
    Department of Chemical Science & Technology, Faculty of Engineering, Kyushu University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Aqueous solutions containing a boronic-acid-appended amphiphile with a L-glutamate segment were gelatinized in the presence of certain saccharides. Examination of the gelation temperature, DSC, and the absorption spectra of a cyanine dye revealed that this is a novel system having two phase-transitions, viz., the sol-gel phase transition and the gel-liquid crystal phase transition.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 27 (10), 1035-1036, 1998-10-01

    Oxford University Press (OUP)

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