Enhanced Molecular-Shape Selectivity for Polyaromatic Hydrocarbons through Isotropic-to-Crystalline Phase Transition of Poly(octadecyl acrylate)

• Hirotaka Ihara

  Department of Applied Chemistry and Biochemistry, Kumamoto University

• Yoshihiro Goto

  Department of Applied Chemistry and Biochemistry, Kumamoto University

• Toshihiko Sakurai

  Department of Applied Chemistry and Biochemistry, Kumamoto University

• Makoto Takafuji

  Department of Applied Chemistry and Biochemistry, Kumamoto University

• Takashi Sagawa

  Institute of Advanced Energy, Kyoto University

• Shoji Nagaoka

  Kumamoto Industrial Research Institute

Abstract

We report temperature-triggered enhancement of molecular-shape selectivity by poly(octadecyl acrylate) which undergoes isotropic-to-crystalline phase transition. In this communication, it is also proposed that π–π interaction is included in this selective interaction and is enhanced through orientation of the carbonyl groups which are in a crystalline state.

Journal

• Chemistry Letters

  Chemistry Letters 30 (12), 1252-1253, 2001-12-01

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360002219109945728
• NII Article ID: 10007541006
• NII Book ID: AA00603318
• DOI: 10.1246/cl.2001.1252
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/30/12/1252/56081157/cl.2001.1252.pdf
• Data Source:
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  • CiNii Articles