A Novel Ring Expansion of the Holey Ketolactam Derivative of C60

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  • Sho-ichi Iwamatsu
    Graduate School of Environmental Studies, Nagoya UniversityNagoya
  • Fumiaki Ono
    Graduate School of Environmental Studies, Nagoya UniversityNagoya
  • Shizuaki Murata
    Graduate School of Environmental Studies, Nagoya UniversityNagoya

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Abstract

<jats:title>Abstract</jats:title> <jats:p>The migrative addition reaction of phenylhydrazine to the ketolactam derivative of C60 occurred with a regioselective cage scission to give a 15-membered ring-opened fullerene bearing a methylene carbon and an acenaphthenequinone monophenylhydrazone unit along the orifice.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 32 (7), 614-615, 2003-06-17

    Oxford University Press (OUP)

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