A Simple, Effective and Highly Selective Cleavage of 3-Methylbut-2-enyl (prenyl) Ethers Using <i>p</i>-Toluenesulfonic Acid

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  • K Suresh Babu
    Natural Products Laboratory, Organic Chemistry Division-1, Indian Institute of Chemical TechnologyHyderabad-500 007 , India
  • B China Raju
    Natural Products Laboratory, Organic Chemistry Division-1, Indian Institute of Chemical TechnologyHyderabad-500 007 , India
  • P V Srinivas
    Natural Products Laboratory, Organic Chemistry Division-1, Indian Institute of Chemical TechnologyHyderabad-500 007 , India
  • A Sridhar Rao
    Natural Products Laboratory, Organic Chemistry Division-1, Indian Institute of Chemical TechnologyHyderabad-500 007 , India
  • S Praveen Kumar
    Natural Products Laboratory, Organic Chemistry Division-1, Indian Institute of Chemical TechnologyHyderabad-500 007 , India
  • J Madhusudana Rao
    Natural Products Laboratory, Organic Chemistry Division-1, Indian Institute of Chemical TechnologyHyderabad-500 007 , India

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Abstract

<jats:title>Abstract</jats:title> <jats:p>A highly selective cleavage of prenyl ethers has been achieved in high yields using p-toluenesulfonic acid under extremely mild conditions. This method is compatible with a wide variety of functional groups such as methyl, benzyl, allyl ethers and benzyl, methyl, prenyl esters present in the molecules.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 32 (8), 704-705, 2003-07-14

    Oxford University Press (OUP)

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