Peak Formation Due to Chemiluminescence Reaction through the Collapse of Laminar Flow Liquid-Liquid Interface in a Microreactor
-
- Tsukagoshi Kazuhiko
- Department of Chemical Engineering and Materials Science, Faculty of Engineering, Doshisha University
-
- Ikegami Keiichi
- Department of Chemical Engineering and Materials Science, Faculty of Engineering, Doshisha University
-
- Nakajima Riichiro
- Department of Chemical Engineering and Materials Science, Faculty of Engineering, Doshisha University
-
- Yamashita Kenichi
- Micro-space Chemistry Laboratory, National Institute of Advanced Industrial Science and Technology
-
- Maeda Hedeaki
- Micro-space Chemistry Laboratory, National Institute of Advanced Industrial Science and Technology
Search this article
Abstract
A peak signal due to a chemiluminescence (CL) reaction in a microreactor consisting of a microchannel without sample plug formation is presented. The CL reaction of luminol–hydrogen peroxide–Cu(II) was used in this study. A CL profile, including a peak signal, was observed by the collapse of the liquid–liquid interface based on laminar flow in the microchannel. We examined CL profiles for various flow rates of reagents and detection points in the microreactor. The data obtained were taken into consideration, together with the residence times and diffusion lengths. On the basis of on the measurements of peak height, Cu(II) was determined over the range of 20 nM–0.1 mM with a detection limit of 20 nM (S/N = 3).
Journal
-
- Chemistry Letters
-
Chemistry Letters 33 (9), 1178-1179, 2004
The Chemical Society of Japan
- Tweet
Keywords
Details 詳細情報について
-
- CRID
- 1390282679557883904
-
- NII Article ID
- 10013527889
-
- NII Book ID
- AA00603318
-
- ISSN
- 13480715
- 03667022
-
- Text Lang
- en
-
- Data Source
-
- JaLC
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Disallowed