New Triggering System for Dioxetane-based Chemiluminescence: Base-induced Decomposition of Bicyclic Dioxetanes Bearing a 3-Aminophenyl or 2-Phenylindol-6-yl Moiety

• Nobuko Watanabe

  Department of Chemistry, Kanagawa University

• Miho Ichikawa

  Department of Chemistry, Kanagawa University

• Ayumi Ono

  Department of Chemistry, Kanagawa University

• Hiroyuki Murakami

  Department of Chemistry, Kanagawa University

• Masakatsu Matsumoto

  Department of Chemistry, Kanagawa University

Abstract

A dioxetane substituted with a 3-aminophenyl group was deprotonated with t-BuOK in DMSO to give an unstable dioxetane bearing a phenylamide anion, which decomposed with accompanying emission of flash red light. Dioxetane bearing an indol-6-yl group was synthesized and found to exhibit emission of flash blue light on treatment with tetrabutylammonium fluoride as well as with t-BuOK.

Journal

• Chemistry Letters

  Chemistry Letters 34 (5), 718-719, 2005-04-16

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360002219110699776
• NII Article ID: 10015544082
• NII Book ID: AA00603318
• DOI: 10.1246/cl.2005.718
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/34/5/718/55586077/cl.2005.718.pdf
• Data Source:
  • Crossref
  • CiNii Articles