Synthesis and Reactivity of Tris(7-azaindolyl)boratoruthenium Complex. Comparison with Poly(methimazolyl)borate Analogue

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  • Tomoyuki Saito
    Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Shigeki Kuwata
    Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology
  • Takao Ikariya
    Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology

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Abstract

<jats:title>Abstract</jats:title> <jats:p>A reaction of [Cp*RuCl]4 (Cp* = η5-C5(CH3)5) with K[HB(aza)3] (aza = 7-azaindolyl) afforded the first organometallic HB(aza)3− complex [Cp*Ru{HB(aza)3-κ3H,N,N′}], which lost one of the aza-units coordination upon treatment with carbon monoxide to give the mono(carbonyl) complex [Cp*Ru{HB(aza)3-κ2H,N}(CO)]. The crystal structures of these complexes have been determined by X-ray crystallography.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 35 (11), 1224-1225, 2006-09-30

    Oxford University Press (OUP)

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