Scandium Ion-accelerated Scavenging Reaction of Cumylperoxyl Radical by a Cyclic Nitroxyl Radical via Electron Transfer

  • Ikuo Nakanishi
    Redox Regulation Research Group, Research Center for Radiation Safety, National Institute of Radiological Sciences (NIRS)
  • Kumiko Kawaguchi
    Redox Regulation Research Group, Research Center for Radiation Safety, National Institute of Radiological Sciences (NIRS)
  • Kei Ohkubo
    Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST, Japan Science and Technology Agency (JST)
  • Tomonori Kawashima
    Redox Regulation Research Group, Research Center for Radiation Safety, National Institute of Radiological Sciences (NIRS)
  • Sushma Manda
    Redox Regulation Research Group, Research Center for Radiation Safety, National Institute of Radiological Sciences (NIRS)
  • Hideko Kanazawa
    Department of Physical Pharmaceutical Chemistry, Kyoritsu University of Pharmacy
  • Keizo Takeshita
    Faculty of Pharmaceutical Sciences, Sojo University
  • Kazunori Anzai
    Redox Regulation Research Group, Research Center for Radiation Safety, National Institute of Radiological Sciences (NIRS)
  • Toshihiko Ozawa
    Redox Regulation Research Group, Research Center for Radiation Safety, National Institute of Radiological Sciences (NIRS)
  • Shunichi Fukuzumi
    Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST, Japan Science and Technology Agency (JST)
  • Nobuo Ikota
    Redox Regulation Research Group, Research Center for Radiation Safety, National Institute of Radiological Sciences (NIRS)

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Abstract

<jats:title>Abstract</jats:title> <jats:p>A cyclic nitroxyl radical used as a spin probe efficiently scavenges cumylperoxyl radical in an aprotic medium via an electron-transfer process, which is significantly accelerated by the presence of scandium ion.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 36 (3), 378-379, 2007-02-03

    Oxford University Press (OUP)

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