The Effects of Hybridization and Hyperconjugation in the Intramolecular Blue-shifted H-Bonds N–H···O

• An Yong Li

  School of Chemistry and Chemical Engineering, Southwest University

Abstract

Theoretical study of an example of intramolecular blue-shifted H-bond N–H···O shows that the blue shift of the N–H bond is caused by an increase in s-character of the N-hybrid AO of the N–H bond upon formation of the H-bond. The effect of hyperconjugation was also analyzed.

Journal

• Chemistry Letters

  Chemistry Letters 37 (6), 596-597, 2008-04-26

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360846644041293952
• NII Article ID: 10021081049
• NII Book ID: AA00603318
• DOI: 10.1246/cl.2008.596
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/37/6/596/55596274/cl.2008.596.pdf
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  • CiNii Articles