Synthesis and Photophysical Properties of Tris-bridged [3.3.<i>n</i>](3,6,9)Carbazolophanes

  • Keita Tani
    Division of Natural Science, Osaka Kyoiku University
  • Naoki Sakumoto
    Division of Natural Science, Osaka Kyoiku University
  • Koji Kubono
    Division of Natural Science, Osaka Kyoiku University
  • Kazushige Hori
    Division of Natural Science, Osaka Kyoiku University
  • Yasuo Tohda
    Division of Natural Science, Osaka Kyoiku University
  • Hiroaki Benten
    Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University
  • Hideo Ohkita
    Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University
  • Shinzaburo Ito
    Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University
  • Masahide Yamamoto
    Faculty of Science and Engineering, Ritsumeikan University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Tris-bridged [3.3.n](3,6,9)carbazolophanes 1n (n=3–6), which are appropriate model compounds for fully overlapped excimer in carbazole chromophore, have been synthesized and characterized by NMR, X-ray, absorption and fluorescence spectra; 1n showed excimeric fluorescence, whose emission maxima strongly depended on the angles and distances between carbazole rings.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 38 (2), 140-141, 2009-01-10

    Oxford University Press (OUP)

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