Oxidative Arylation Mediated by Naphthalene-1,8-diylbis(diphenylmethylium): Synthetic Route to Triarylsulfonium Salts

  • Tanabe Hiroyuki
    Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba
  • Kawai Takaharu
    Department of Chemistry, Graduate School of Science, The University of Tokyo
  • Saitoh Terunobu
    Department of Chemistry, Graduate School of Science, The University of Tokyo
  • Ichikawa Junji
    Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba

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Abstract

Dicationic species, naphthalene-1,8-diylbis(diphenylmethylium), successfully promoted oxidative arylation of the sulfur atom in (4-N,N-dialkylaminophenyl) phenyl sulfides with (4-N,N-dialkylaminopheny)silanes, affording triarylsulfonium salts in good yield.

Journal

  • Chemistry Letters

    Chemistry Letters 39 (1), 56-57, 2010

    The Chemical Society of Japan

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