Nickel-catalyzed Cycloadditions of Benzoxazinones with Alkynes: Synthesis of Quinolines and Quinolones

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  • Nobuyoshi Maizuru
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University
  • Tasuku Inami
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University
  • Takuya Kurahashi
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University
  • Seijiro Matsubara
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>A nickel-catalyzed cycloaddition has been developed where readily available benzoxazinones react with alkynes to afford substituted quinolines or quinolones. The specific cycloaddition can be achieved by tuning a substituent on C2 of benzoxazinone in favor of the formation of quinolines or quinolones selectively.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 40 (4), 375-377, 2011-03-05

    Oxford University Press (OUP)

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