Introduction of Two Anthracene Moieties into Perylenebis(dicarboximide) Core by Suzuki–Miyaura Coupling toward Construction of Donor–Acceptor–Donor Arrays

• Tetsuo Iwanaga

  Department of Chemistry, Faculty of Science, Okayama University of Science

• Hiroko Ida

  Department of Chemistry, Faculty of Science, Okayama University of Science

• Makoto Takezaki

  Department of Applied Chemistry, Faculty of Engineering, Okayama University of Science

• Shinji Toyota

  Department of Chemistry, Faculty of Science, Okayama University of Science

Abstract

To create new π-conjugated compounds having a donor–acceptor–donor array, two 4-(9-anthrylethynyl)phenyl groups were introduced into a perylenebis(dicarboximide) structure at 1,6- or 1,7-positions by the Suzuki–Miyaura coupling of corresponding dibromoperylenebis(dicarboximide) and boronic acid ester derivatives. The UV–vis and fluorescence spectra and the electrochemical data of these donor–acceptor–donor type compounds suggested weak electronic interactions between the anthracene units and the perylenebis(dicarboximide) unit.

Journal

• Chemistry Letters

  Chemistry Letters 40 (9), 970-971, 2011-09

  Oxford University Press (OUP)

Details

• CRID: 1360002219111594496
• NII Article ID: 10029522142
• NII Book ID: AA00603318
• DOI: 10.1246/cl.2011.970
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/40/9/970/55606442/cl.2011.970.pdf
• Data Source:
  • Crossref
  • CiNii Articles
  • KAKEN