A <i>mer</i>-Triaqua Rh Complex with a Terpyridine Ligand

DOI PDF 37 References
  • Daisuke Inoki
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Takahiro Matsumoto
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Hidetaka Nakai
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Seiji Ogo
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University

Search this article

Abstract

<jats:title>Abstract</jats:title> <jats:p>We report the synthesis of a mer-triaqua RhIII complex using terpyridine as a meridional tridentate ligand. This is the first example of a structurally characterized six-coordinated mer-triaqua complex for any second- or third-row element from the main transition-metal groups (groups 5–11). This is also the first example of a structurally characterized mer-triaqua complex with terpyridine for any transition metal. Acid dissociation constants, pKa1 and pKa2, of the triaqua complex are determined to be 3.0 and 6.9, respectively.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 41 (1), 116-118, 2011-12-30

    Oxford University Press (OUP)

References(37)*help

See more

Related Projects

See more

Keywords

Details 詳細情報について

Report a problem

Back to top