Ru/Ag-Catalyzed Oxidative Alkenylation of Benzamides and Phenylazoles through Regioselective C–H Bond Cleavage

• Yuto Hashimoto

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Timon Ortloff

  Institute of Organic Chemistry, RWTH Aachen University

• Koji Hirano

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Tetsuya Satoh

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

• Carsten Bolm

  Institute of Organic Chemistry, RWTH Aachen University

• Masahiro Miura

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

Abstract

Oxidative alkenylation of N,N-disubstituted benzamides with alkenes accompanied by regioselective C–H bond cleavage proceeds efficiently in the presence of a Ru/Ag catalyst system together with a copper oxidant. The procedure is also applicable to phenylazoles.

Journal

• Chemistry Letters

  Chemistry Letters 41 (2), 151-153, 2012-01-28

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360565169065065216
• NII Article ID: 10030223153
• NII Book ID: AA00603318
• DOI: 10.1246/cl.2012.151
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/41/2/151/55641092/cl.2012.151.pdf
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