Specific Chromatographic Retentions on Polymer Pore Surface of Macroporous Spongy Monoliths

• Tanigawa, Tetsuya

• Kubo, Takuya

• Hosoya, Ken

Abstract

We examined chromatographic retention properties of macroporous spongy monolithic columns. Detailed chromatographic evaluations showed that planar compounds were strongly retained on poly(ethylene-co-vinyl acetate)-based monoliths, whereas sterically bulky or hydrophilic compounds were weakly retained. The comparison results with commonly used columns suggested that the specific retention abilities were a result of the differences in the polymer-chain orientation on polymer pore surface.

Journal

• Chemistry Letters

  Chemistry Letters 41 (10), 1265-1266, 2012-10-05

  Chemical Society of Japan

Keywords

• General Chemistry

Details

• CRID: 1050282810779275520
• NII Article ID: 10031120653
• NII Book ID: AA00603318
• ISSN: 03667022
• ISSN: 13480715
• DOI: 10.1246/cl.2012.1265
• HANDLE: 2433/193756
• Web Site: https://academic.oup.com/chemlett/article-pdf/41/10/1265/55637997/cl.2012.1265.pdf
• Text Lang: en
• Article Type: journal article
• Data Source:
  • IRDB
  • Crossref
  • CiNii Articles
  • KAKEN