Synthesis of Substituted Sumanenes by Aromatic Electrophilic Substitution Reactions

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  • Binod Babu Shrestha
    Department of Functional Molecular Science, School of Physical Sciences, The Graduate University for Advanced Studies
  • Sangita Karanjit
    Department of Functional Molecular Science, School of Physical Sciences, The Graduate University for Advanced Studies
  • Gautam Panda
    Research Center for Molecular Scale Nanoscience, Institute for Molecular Science
  • Shuhei Higashibayashi
    Department of Functional Molecular Science, School of Physical Sciences, The Graduate University for Advanced Studies
  • Hidehiro Sakurai
    Department of Functional Molecular Science, School of Physical Sciences, The Graduate University for Advanced Studies

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Electrophilic substitution reactions of sumanene were studied. Mono-, di-, and trisubstituted sumanenes were selectively prepared with the separation of all regioisomers. The regioselectivity was predicted well by the HOMO density values determined by DFT calculations.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 42 (4), 386-388, 2013-03-19

    Oxford University Press (OUP)

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