Copper-catalyzed 1,4-Addition Reaction of Grignard Reagent to Enones Using Microflow System

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  • Haruo Katayama
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University
  • Seijiro Matsubara
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>The copper-catalyzed conjugate addition of a Grignard reagent to an α,β-unsaturated ketone was performed in a microflow system. In the reaction using the microflow system, a chemoselective 1,4-addition reaction to an enone in the presence of a saturated ketone group proceeded successfully.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 42 (5), 471-472, 2013-03-22

    Oxford University Press (OUP)

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