Oxidation States of [5]Radialene with Five 1,3-Dithiol-2-ylidenes and Its Oxygen Adduct

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  • Masafumi Ueda
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Takashi Shirahata
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Yohji Misaki
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Spectroelectrochemistry of [5]radialenes with five 1,3-dithiol-2-ylidenes (DTs) (1) was carried out. The UV–vis–NIR spectra of 12+ suggest delocalization of two positive charges over three DT units. X-ray structure analysis of an oxygen adduct (2)2+(AsF6−)2(PhCl)1.5 reveals that 22+ has a cyclopentadienide structure in the central five-membered ring.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 42 (5), 565-567, 2013-04-24

    Oxford University Press (OUP)

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