Synthesis of Diverse Aromatic Oxophosphorus Compounds by the Michaelis–Arbuzov-type Reaction of Arynes

• Suguru Yoshida

  Laboratory of Chemical Bioscience, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University

• Takamitsu Hosoya

  Laboratory of Chemical Bioscience, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University

Abstract

Arynes, generated in situ from o-(trimethylsilyl)aryl triflates by treatment with a fluoride, have been shown to react efficiently with various alkoxyphosphines via a mechanism similar to the Michaelis–Arbuzov reaction. Diverse aromatic oxophosphorus compounds, including derivatives with an ortho-ester function, have become easily available from a common aryne precursor by this method.

Journal

• Chemistry Letters

  Chemistry Letters 42 (6), 583-585, 2013-05-03

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360283694082080640
• NII Article ID: 10031176015
• NII Book ID: AA00603318
• DOI: 10.1246/cl.130116
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/42/6/583/55634810/cl.130116.pdf
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