Laser Desorption Supersonic Jet Spectroscopy of Octopamine by Its Hydrochloride Salt
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- Shun-ichi Ishiuchi
- Chemical Resources Laboratory, Tokyo Institute of Technology
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- Hirokazu Sone
- Chemical Resources Laboratory, Tokyo Institute of Technology
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- Masaaki Fujii
- Chemical Resources Laboratory, Tokyo Institute of Technology
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Abstract
<jats:title>Abstract</jats:title> <jats:p>Octopamine is a phenol analog of noradrenaline and acts as a neurotransmitter in invertebrates such as octopus. It is available as a hydrochloride salt to avoid air oxidation. We applied laser desorption supersonic jet technique to octopamine hydrochloride without any chemical preparations and found that molecular ion of octopamine, not salt, is observed. Resonance-enhanced 2-photon ionization and ultraviolet–ultraviolet hole-burning spectra of octopamine were measured, and four conformers were identified. This number of conformations is rationalized by conformations of ethanolamine chain and orientations of phenolic OH.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 42 (10), 1166-1167, 2013-06-11
Oxford University Press (OUP)
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Keywords
Details 詳細情報について
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- CRID
- 1360002219105410560
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- NII Article ID
- 10031201297
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- NII Book ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles
- KAKEN