Nickel-catalyzed Decarbonylative and Decarboxylative Cycloaddition of Isatoic Anhydrides with Alkynes

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  • Kenichiro Nakai
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University
  • Takuya Kurahashi
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University
  • Seijiro Matsubara
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University

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Abstract

<jats:title>Abstract</jats:title> <jats:p>We have developed a nickel-catalyzed cycloaddition of isatoic anhydrides with alkynes to afford 2,3-disubstituted indoles. The reaction proceeds via the elimination of carbon monoxide and carbon dioxide and the insertion of alkynes.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 42 (10), 1238-1240, 2013-10

    Oxford University Press (OUP)

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