Iron Corrole-catalyzed [4 + 2] Cycloaddition of Dienes and Aldehydes

• Toru Kuwano

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Takuya Kurahashi

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Seijiro Matsubara

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

Abstract

We have developed cationic iron(IV) corrole-catalyzed formal hetero-Diels–Alder reaction of aldehydes with dienes, which opens the way for divergent synthesis of pyrans. The potential utility of the catalyst was also demonstrated by carrying out cycloaddition of α,β-unsaturated aldehyde with a diene to give pyran selectively. Furthermore, the catalytic reactivity of iron corrole complex on the cycloaddition was determined by comparing that of iron porphyrin complex.

Journal

• Chemistry Letters

  Chemistry Letters 42 (10), 1241-1243, 2013-10

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360565169058856960
• NII Article ID: 10031201324
• NII Book ID: AA00603318
• DOI: 10.1246/cl.130672
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/42/10/1241/55636586/cl.130672.pdf
• Data Source:
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