Macrocyclization and reaction of macrocyclic enolates 大員環形成反応と大環状エノラートの反応

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Author

    • 灰野, 岳晴 ハイノ, タケハル

Bibliographic Information

Title

Macrocyclization and reaction of macrocyclic enolates

Other Title

大員環形成反応と大環状エノラートの反応

Author

灰野, 岳晴

Author(Another name)

ハイノ, タケハル

University

広島大学

Types of degree

理学博士

Grant ID

乙第2322号

Degree year

1992-11-16

Note and Description

博士論文

Table of Contents

  1. Contents / (0008.jp2)
  2. Chapter1 Introduction / p1 (0011.jp2)
  3. 1-1 Organic Synthesis and Theoretical Prediction / p1 (0011.jp2)
  4. 1-2 Molecular Mechanics and Conformational Analysis / p5 (0015.jp2)
  5. Chapter2 Cyclization of Medium Ring System / p13 (0023.jp2)
  6. 2-1 Medium and Large Ring Natural Compounds and Cyclization Reaction / p13 (0023.jp2)
  7. 2-2 Cyclization Reaction / p22 (0032.jp2)
  8. 2-3 Conclusion / p34 (0044.jp2)
  9. Chapter3 Construction of Large Rings Based on Molecular Design for Reactive Intermediates. Application to the Synthesis of Muscone / p37 (0047.jp2)
  10. 3-1 Muscone as a Challenging Synthetic Target / p37 (0047.jp2)
  11. 3-2 Synthesis of C₂ Symmetric Macro Ring Natural Product and Dianion Methodology / p38 (0048.jp2)
  12. 3-3 Molecular Design and Dianion Methodology / p40 (0050.jp2)
  13. 3-4 Syntheses of Cyclization Precursors and the Cyclization Reaction / p46 (0056.jp2)
  14. 3-5 Synthesis of Muscone / p56 (0066.jp2)
  15. 3-6 Conclusion / p57 (0067.jp2)
  16. Chapter4 Face Selectivity of Macrocyclic Enone System: Toward the Synthesis of Steroid Skeleton / p62 (0072.jp2)
  17. 4-1 Steroid as a Synthetic Target / p62 (0072.jp2)
  18. 4-2 Synthetic Strategy of Steroid Skeleton / p64 (0074.jp2)
  19. 4-3 π-Orbitais in Macrocyclic System / p67 (0077.jp2)
  20. 4-4 Stereochemistry of Michael Addition of Macrocyclic Trans Enone and Electrophilic Trap of the Subsequent Enolate Anion / p69 (0079.jp2)
  21. 4-5 Stereochemistry of Enone Switching Reaction in Macrocyclic Compound / p80 (0090.jp2)
  22. 4-6 Conclusion / p95 (0105.jp2)
  23. Experimental Section / p99 (0109.jp2)
  24. Synthesis of Medium Ring 1,5-Dienes / p527 (0228.jp2)
  25. Dianion Methodology for the Construction of Large-Membered Ring Systems: Application to the Synthesis of Muscone. / (0232.jp2)
  26. Synthesis and Structure of 1,10-ο-Benzeno[2.2]orthocyclophane-ο-quinones.Evaluation of Attractive Energy between Donor and Acceptor / p957 (0237.jp2)
  27. Enolate Reactions on Macrocyclic Ring Systems.Total Synthesis of (±)-Sarcophytol A† / (0241.jp2)
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Codes

  • NII Article ID (NAID)
    500000091657
  • NII Author ID (NRID)
    • 8000000091882
  • DOI(NDL)
  • NDLBibID
    • 000000255971
  • Source
    • NDL ONLINE
    • NDL Digital Collections
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