Macrocyclization and reaction of macrocyclic enolates 大員環形成反応と大環状エノラートの反応
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著者
書誌事項
- タイトル
-
Macrocyclization and reaction of macrocyclic enolates
- タイトル別名
-
大員環形成反応と大環状エノラートの反応
- 著者名
-
灰野, 岳晴
- 著者別名
-
ハイノ, タケハル
- 学位授与大学
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広島大学
- 取得学位
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理学博士
- 学位授与番号
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乙第2322号
- 学位授与年月日
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1992-11-16
注記・抄録
博士論文
目次
- Contents / (0008.jp2)
- Chapter1 Introduction / p1 (0011.jp2)
- 1-1 Organic Synthesis and Theoretical Prediction / p1 (0011.jp2)
- 1-2 Molecular Mechanics and Conformational Analysis / p5 (0015.jp2)
- Chapter2 Cyclization of Medium Ring System / p13 (0023.jp2)
- 2-1 Medium and Large Ring Natural Compounds and Cyclization Reaction / p13 (0023.jp2)
- 2-2 Cyclization Reaction / p22 (0032.jp2)
- 2-3 Conclusion / p34 (0044.jp2)
- Chapter3 Construction of Large Rings Based on Molecular Design for Reactive Intermediates. Application to the Synthesis of Muscone / p37 (0047.jp2)
- 3-1 Muscone as a Challenging Synthetic Target / p37 (0047.jp2)
- 3-2 Synthesis of C₂ Symmetric Macro Ring Natural Product and Dianion Methodology / p38 (0048.jp2)
- 3-3 Molecular Design and Dianion Methodology / p40 (0050.jp2)
- 3-4 Syntheses of Cyclization Precursors and the Cyclization Reaction / p46 (0056.jp2)
- 3-5 Synthesis of Muscone / p56 (0066.jp2)
- 3-6 Conclusion / p57 (0067.jp2)
- Chapter4 Face Selectivity of Macrocyclic Enone System: Toward the Synthesis of Steroid Skeleton / p62 (0072.jp2)
- 4-1 Steroid as a Synthetic Target / p62 (0072.jp2)
- 4-2 Synthetic Strategy of Steroid Skeleton / p64 (0074.jp2)
- 4-3 π-Orbitais in Macrocyclic System / p67 (0077.jp2)
- 4-4 Stereochemistry of Michael Addition of Macrocyclic Trans Enone and Electrophilic Trap of the Subsequent Enolate Anion / p69 (0079.jp2)
- 4-5 Stereochemistry of Enone Switching Reaction in Macrocyclic Compound / p80 (0090.jp2)
- 4-6 Conclusion / p95 (0105.jp2)
- Experimental Section / p99 (0109.jp2)
- Synthesis of Medium Ring 1,5-Dienes / p527 (0228.jp2)
- Dianion Methodology for the Construction of Large-Membered Ring Systems: Application to the Synthesis of Muscone. / (0232.jp2)
- Synthesis and Structure of 1,10-ο-Benzeno[2.2]orthocyclophane-ο-quinones.Evaluation of Attractive Energy between Donor and Acceptor / p957 (0237.jp2)
- Enolate Reactions on Macrocyclic Ring Systems.Total Synthesis of (±)-Sarcophytol A† / (0241.jp2)
