Construction of cyclic compounds using organozirconium complexes 有機ジルコニウム錯体を用いた環状化合物の構築

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Author

    • 劉, 元紅 リュウ, ユェンホン

Bibliographic Information

Title

Construction of cyclic compounds using organozirconium complexes

Other Title

有機ジルコニウム錯体を用いた環状化合物の構築

Author

劉, 元紅

Author(Another name)

リュウ, ユェンホン

University

北海道大学

Types of degree

博士 (薬学)

Grant ID

甲第5103号

Degree year

2000-03-24

Note and Description

博士論文

Table of Contents

  1. Contents / (0003.jp2)
  2. Chapter 1.General Introduction to Organozirconium Chemistry and Its Use in the Preparation of Cyclic Compounds / p1 (0006.jp2)
  3. 1.1 Hydrozirconation of Alkenes or Alkynes / p2 (0007.jp2)
  4. 1.2 Zirconocene (II) Species in Organic Synthesis / p4 (0009.jp2)
  5. 1.3 The Synthetic Utilities of Zirconacycles in The Construction of Cyclized Compounds / p9 (0014.jp2)
  6. References and Notes / p16 (0021.jp2)
  7. Chapter 2.Formation of 4-Membered Carbocycles I: Reductive Elimination of α-Alkynyl Substituted Zirconacyclopentenes: Formation of Cyclobutene Derivatives / p20 (0025.jp2)
  8. Introduction / p21 (0026.jp2)
  9. Results and Discussion / p21 (0026.jp2)
  10. Experimental Section / p28 (0033.jp2)
  11. General Experimental Section / p28 (0033.jp2)
  12. References and Notes / p34 (0039.jp2)
  13. Chapter 3.Formation of 4-Membered Carbocycles II: Zirconocene-catalyzed Cyclobutene Formation by Reaction of Alkynyl Halides with EtMgBr / p36 (0041.jp2)
  14. Introduction / p37 (0042.jp2)
  15. Results and Discussion / p37 (0042.jp2)
  16. Experimental Section / p43 (0048.jp2)
  17. References and Notes / p46 (0051.jp2)
  18. Chapter 4.Formation of 5 and 6-Membered Carbocycles I: Inter-or Intramolecular Carbometallation of Nonactivated Alkynes by Zirconacycles in the Presence of Copper Chloride / p48 (0053.jp2)
  19. 4.1 Alkynylation of Zirconacycles in the Presence of CuCl / p49 (0054.jp2)
  20. 4.2 Inter-or Intramolecular Carbometallation of Nonactivated Alkynes by Zirconacyclopentanes or-pentenes / p53 (0058.jp2)
  21. Experimental Section / p62 (0067.jp2)
  22. References and Notes / p74 (0079.jp2)
  23. Chapter 5.Formation of 5 and 6-Membered Carbocycles II: Cycloaddition Reaction of Zirconacyclopentadienes to Alkynes: Formation of Benzene or Cyclopentadiene Derivatives by Different Reaction Pathways / p77 (0082.jp2)
  24. 5.1 Cycloaddition of Zirconacyclopentadienes to an Electron-deficient Alkynes:Formation of Benzene Derivatives / p78 (0083.jp2)
  25. 5.2 Mechanism of Cycloaddition Reaction of Zirconacyclopentadienes to Dimethyl Acetylenedicarboxylate / p79 (0084.jp2)
  26. 5.3 Cycloaddition of Zirconacyclopentadienes with Electron-deficient Alkynes: Formation of Cyclopentadiene Derivatives / p86 (0091.jp2)
  27. Experimental Section / p89 (0094.jp2)
  28. References and Notes / p96 (0101.jp2)
  29. Chapter 6.Formation of 6-Membered Carbocycles:Direct Michael Addition of Zircona-cyclopentanes and-pentenes to Activated Alkenes / p100 (0105.jp2)
  30. Introduction / p101 (0106.jp2)
  31. Results and Discussion / p101 (0106.jp2)
  32. Experimental Section / p111 (0116.jp2)
  33. References and Notes / p124 (0129.jp2)
  34. Chapter 7.Formation of 8-Membered Carbocycles: Novel and Stereocontrolled Synthesis of 8-Membered Carbocycles by Zirconacyclopentadienes / p126 (0131.jp2)
  35. Introduction / p127 (0132.jp2)
  36. Results and Discussion / p127 (0132.jp2)
  37. Experimental Section / p133 (0138.jp2)
  38. References and Notes / p136 (0141.jp2)
  39. Chapter 8.Zirconium Catalyzed C-C Bond Formation of Imines with EtMgBr / p139 (0144.jp2)
  40. Introduction / p140 (0145.jp2)
  41. Results and Discussion / p140 (0145.jp2)
  42. Experimental Section / p144 (0149.jp2)
  43. References and Notes / p146 (0151.jp2)
  44. List of Publications / p147 (0152.jp2)
  45. Acknowledgments / p150 (0155.jp2)
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Codes

  • NII Article ID (NAID)
    500000189546
  • NII Author ID (NRID)
    • 8000000189829
  • DOI(NDL)
  • NDLBibID
    • 000000353860
  • Source
    • NDL ONLINE
    • NDL Digital Collections

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