書誌事項

Microwave molecular spectra

Walter Gordy, Robert L. Cook

(Techniques of chemistry, v. 18)

Wiley, c1984

3rd ed

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注記

"A Wiley-Interscience publication."

Includes bibliographies and indexes

内容説明・目次

内容説明

Many exciting new developments in microwave spectroscopy have occurred since the earlier edition of this book was published in 1970. The frequency coverage of coherent microwave spectroscopy is still expanding. Although not comparable to the fourfold expansion that occurred in the 17 years preceding the 1970 edition, the millimeter wave range has been extended from 800 GHz to above 100 GHz since 1970. Subtle new techniques continue to improve the sensitivity and resolving power of microwave spectrometers as well as their applicability to new types of spectra. Although the spectra described in the earlier edition are in no sense out of date, the new developments made the revision of Microwave Molecular Spectra desirable if not necessary. Because the authors could not justifiably delete nor significantly reduce the basic material of the earlier edition, a moderate expansion of the volume was necessary to achieve an adequate coverage of microwave molecular spectra in the 1980's.

目次

  • Introduction
  • Theoretical Aspects of Molecular Rotation
  • Microwave Transitions - Line Intensities and Shapes
  • Diatomic Molecules
  • Linear Polyatomic Molecules
  • Symmetric-Top Molecules
  • Asymmetric-Top Molecules
  • The Distortable Rotor
  • Nuclear Hyperfine Structure in Molecular Rotational Spectra
  • Effects of Applied Electric Fields
  • Effects of Applied Magnetic Fields
  • Internal Motions
  • Derivation of Molecular Structures
  • Quadrupole Couplings, Dipole Moments, and the Chemical Bond
  • Irreducible Tensor Methods for Calculation of Complex Spectra
  • Appendixes
  • Author Index
  • Subject Index.

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