Activation of alkenes and alkynes
著者
書誌事項
Activation of alkenes and alkynes
(Homogeneous catalysis by metal complexes / [by] M. M. Taqui Khan [and] Arthur E. Martell, v. 2)
Academic Press, 1974
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注記
Includes bibliographical references
内容説明・目次
内容説明
Homogeneous Catalysis by Metal Complexes, Volume II: Activation of Alkenes and Alkynes reviews and systematizes the chemistry of metal ion activation of alkenes and alkynes. The book presents the migration of ? bonds; the oxo reaction; and the hydrosilation of alkenes and alkynes. The text also covers topics on the oxidation of alkenes and alkynes, as well as the multiple insertion reactions of alkenes and alkynes.
目次
PrefaceContents of Volume I1 Introduction2 Migration of p Bonds I. p-Bond Migration Catalyzed by Metal Carbonyls II. Metal Complex-Catalyzed p-Bond Migration3 The Oxo Reaction I. Introduction II. Reactions of Alkenes III. Hydroformylation of Alkynes IV. Hydrogenation under Oxo Conditions V. Applications of the Oxo Reaction4 Hydrosilation of Alkenes and Alkynes I. Catalysis by Platinum (II) and Rhodium (II) II. Catalysis of Hydrosilation by Metal Carbonyls5 Oxidation of Alkenes and Alkynes I. Oxidation of Alkenes II. Hydration of Alkynes III. Alkene or Alkyne Insertion into Metal-Carbon Bonds6 Multiple Insertion Reactions of Alkenes and Alkynes I. Introduction II. Polymerization of Ethylene and a-Olefins III. Polymerization of Dienes IV. Polymerization of Alkynes V. Oligomerization of Ethylene and a-Olefins VI. Oligomerization of Alkynes VII. Cyclic Oligomerization of AlkynesBibliographyAppendix I Formulas, Bonding, and Formal ChargesAppendix II Glossary of Terms and AbbreviationsAuthor IndexSubject Index
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