Organic solid state chemistry
著者
書誌事項
Organic solid state chemistry
（Studies in organic chemistry, 32）
Elsevier Science, 1987
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
With the growing recognition that many organic reactions may be conducted easily in the solid state and that organic solids may have unique optical/electronic properties, there has been much interest - in both academia and industry - in the subject of organic solid state chemistry. This book provides, for the first time, a coherent, unified view of the subject. It describes the packing of molecular crystals and how this packing influences chemical reactions in the solid state. It is concerned with various means of studying the chemistry and physics of molecules in constrained environments. Both experimental and theoretical approaches are discussed. Finally, it tackles the question of prediction of crystal packing, or `crystal engineering'. The strength of the book lies in the twin approach adopted, namely that both conceptual and comprehensive chapters are present, in almost equal numbers.
目次
Organic Solid State Reactions: Topochemistry and Mechanism. Geometric Requirements for Intramolecular Photochemical Hydrogen Atom Abstraction: Studies Based on a Combination of Solid State Chemistry and X-Ray Crystallography (J.R. Scheffer). Topotactic and Topochemical Photodimerisation of Benzylidenecyclopentanones (C.R. Theocharis, W. Jones). The Prediction of Chemical Reactivity Within Organic Crystals Using Geometric Criteria (S.K. Kearsley). Phonon Spectroscopy of Organic Solid State Reactions (P.N. Prasad). Four-Center Type Photopolymerization of Diolefin Crystals (M. Hasegawa). Some Stereochemical Questions: Pure and Applied Chemistry. Organic Molecules in Constrained Environments (J.M. Thomas, K.D.M. Harris). Clathrates (G. Tsoucaris). Solid State Chemistry of Phenols and Possible Industrial Applications (R. Perrin et al.). Gas-Solid Reactions and Polar Crystals (I.C. Paul, D.Y. Curtin). Intermolecular Interactions: From Crystallography to Chemical Physics. Phase Transitions in Organic Solids (C.N.R. Rao). Molecular Motions in Organic Crystals: The Structural Point of View (A. Gavezzotti, M. Simonetta). Interatomic Potentials and Computer Simulations of Organic Molecules in the Solid State (S. Ramdas, N.W. Thomas,). Conformational Polymorphism (J. Bernstein). Crystal Engineering A 4 A - Short Axis Structure for Planar Chloro Aromatics (G.R. Desiraju).
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