Inorganic syntheses

著者

• Booth, Harold Simmons
• Audrieth, L. F. (Ludwig Frederick)
• Sloan, Thomas E.

書誌事項

Inorganic syntheses

editor-in-chief, Harold Simmons Booth ; associate editors, L.F. Audrieth ... [et al.]

McGraw-Hill, 1939-

• v. 1
• v. 2
• v. 3
• v. 4
• v. 5
• v. 6
• v. 7
• v. 8
• v. 9
• v. 10
• v. 11
• v. 12
• v. 13
• v. 14
• v. 15
• v. 16
• v. 17
• v. 18
• v. 19
• v. 20
• v. 21
• v. 22
• v. 23
• v. 24
• v. 25
• v. 26
• v. 27
• v. 29
• collective index for v. 1-30
• v. 31
• v. 32
• v. 33
• v. 34
• v. 35
• v. 36
• v. 37

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注記

Includes bibliographies and index

子書誌あり

v. 18-: published by John Wiley & Sons

v. 18-: "A Wiley-Interscience publication"

Editor-in-chief: v. 2: W. Conard Fernelius. v. 3: Ludwig F. Audrieth. v. 4: John C. Bailar, Jr.. v. 5: Therald Moeller. v. 6: Eugene G. Rochow. v. 7: Jacob Kleinberg. v. 8: Henry F. Holtzclaw, Jr.. v. 9: S. Young Tyree, Jr.. v. 10: Earl L. Muetterties. v. 11: William L. Jolly. v. 12: Robert W. Parry. v. 13: F.A. Cotton. v. 14: Aaron Wold, John K. Ruff. v. 15: George W. Parshall. v. 16: Fred Basolo. v. 17: Alan G. MacDiardmid. v. 18: Bodie E. Douglas. v. 19: Duward F. Shriver. v. 20: Daryle H. Busch. v. 21: John P. Fackler, Jr.. v. 22. Smith L. Holt, Jr.. v. 23: Stanley Kirschner. v. 24: Jean'ne M. Shreeve. v. 25: Harry R. Allcock. v. 26: Herbert D. Kaesz. v. 27: Alvin P. Ginsberg. v. 29: Russell N. Grimes. collective index for v. 1-30. Thomas E. Sloan. v. 31 Alan H. Cowley. v. 32: Marcetta York Darensbourg. v. 33: Dimitri Coucouvanis. v. 34: John R. Shapley. v. 35: Thomas B. Rauchfuss. v.36: Gregory S. Girolami, Alfred P. Sattelberger. v.37: Philip P. Power

内容説明・目次

巻冊次

v. 18 ISBN 9780471033936

内容説明

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

巻冊次

v. 19 ISBN 9780471045427

内容説明

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

巻冊次

v. 20 ISBN 9780471077152

内容説明

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

巻冊次

v. 31 ISBN 9780471152880

内容説明

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preperation of important inorganic solidsd, sutheses used in the development of pharamacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains calcuable information on transition organometallic compunds, including species with meta-metal cluster molecules. All syntheses presented here have been tested.

目次

Chapter One MAIN GROUP COMPOUNDS. 1. Volatile-(2) Diketonate Complexes of Calcium(II), Strontium(II), and Barium(II). 2. Bis(1,1,1,3,3,3-hexamethyldisilazanato) bis(tetrahydrofuran)-barium. 3. Ammonium and Barium Salts of the Tris- [1,2-benzenediolate(2-)-O,O']titanium(IV) Dianion. 4. N-Donor Adducts of Dimethylzinc. 5. Arene Chalcogenolato Complexes of Zinc and Cadmium. 6. Arene Thiolato, Selenolato, and Tellurolato Complexes of Mercury. 7. Electronic Grade Alkyls of Group 12 and 13 Elements. 8. Trimethylindium and Trimethylgallium. 9. (N,N-dimethylethanamine) trihydridoafuminum. 10. Tertiary Amine and Phosphine Adducts of Gallium Trihydride. 11. trans-1,1-Di-tert-butyl-2,3-dimethylsilane and 2,2-Di-tert-butyl 1,1,1-triethyldisilane. 12. Tin(II) Sulfide and Tin(II) Selenide. 13. Tin(IV) Fluoride (Tetrafluorostannane). 14. N,N,N'-Tris(trimethylsilyl) Amidines. 15. Homoleptic Bismuth Amides. 16. Cyclo-tetrasulfur(2+) Bis[hexafluoroarsenate(1-)], Cyclo-tetrasulfur(2+)Bis[undecafluorodiantimonate(1-)], Cyclo-tetraselenium(2+)Bis[hexafluroarsenate(1-)] and Cyclo-tetraselenium(2+) Bis[undecafluorodiantimonate(1-)]. 17. Fe2(S2)(CO)6, and Fe3Te2(CO)9,10. Chapter Two LIGANDS AND REAGENTS. 18. 5,10,15,20-Tetrakis (2,6-dihydroxyphenyl) -21H,23H-porphine. 19. Tribenzocycline (TBC) and Tetrabenzocyclyne (QBC). 20. (Chloromethylene)bis[trimethylsilane] [Bis(trimethylsilyl)chloromethane]. 21. S,S-Chiraphos [(S,S)-(-)-(1,2-Dimethyl-1,2-ethandiyl) bis-(diphenylphosphine)]. 22. (2)-Ketophosphines: Ligands of Catalytic Relevance. 23. N,N-Diisobutyl-2-(octylphenylphosphinyl) acetamide (CMPO). 24. Aresenic(III) Chloride. 25. Tris(trimethylsilyl)arsine and Lithium Bis(trimethylsilyl)arsenide. 26. Sterically Hindered Arene Chalcogenols. 27. Tris(trimethylsilyl)silyl Lithium Tris(tetrahydrofuran), Lithium Tris(trimethylsilyl)silyltellurolate Bis(tetrahydrofuran), and Tris(trimethylsilyl)silyltellurol. 28. Metal Complexes of the Lacunary Heteropolytungstates [B-+/--PW9O34]9- and [+/--P2W15O56]12-. 29. Polyoxoanion-Supported, Atomically Dispersed Iridium(I) and Rhodium(I). Chapter Three ORGANOMETALLIC COMPOUNDS. 30. One-Pot Synthesis of Dicarbonyltris(phosphine)iron(0) Complexes from Pentacarbonyliron. 31. Tricarbonylbis(phosphine)iron(0) Complexes. 32. (*5-Pentamethylcyclopentadienyl) (*5-cyclopentadienyl)iron [1,2,3,4,5-pentamethylferrocene]. 33. Pyrazolate-Bridged Ruthenium(I) Carbonyl Complexes. 34. Main Group-Transition Metal Carbonyl Complexes. 35. MnII4(1/44-O)[(CO)9Co3(1/43-CCO2)]6, M = Co, Zn. 36. 1,2,3,4-Tetramethyl-5-(trifluoromethyl)cyclopentadiene (Cp+ H) and Di-1/4-Chlorodichlorobis [*5-tetramethyl- (Trifluoromethyl)Cyclopentadienyl] Dirhodium(III). 37. Acetonitrile-Substituted Derivatives of Rh6(CO)16: Rh6(CO)16-x(NCMe)x(x = 1, 2). 38. Tetraphenylarsonium Carbonyltrichloroplatinate(II). Chapter Four TRANSITION METAL, LANTHANIDE, AND ACTINIDE COMPLEXES. 39. Dichlordioxobis(dimethyl sulphoxide)molybdenum(VI). 40. Metal-Catalyzed Synthesis of cis-[Re(CO)4,LI] [L = P(OMe)3, PMe2Ph, PPh3]. 41. Tris(l,2-bis(dimethylphosphino) ethane)rhenium(1) Trifluoromethanesulfonate, [Re(DMPE)3[CF3SO3]. 42. Tetrahalo Oxorhenate Anions. 43. A Rhenium(I) Dinitrogen Complex Containing a Tertiary Phosphine. 44. Bis(2,4-pentanedionato)iron(II) [Iron(II)Bis(acetylacetonate)]. 45. Synthesis of trans-Tetraammined.ichlorocobalt(III)Chloride. 46. [[3,3'-(1,3-Propanediyldiimino) bis[3-methy-2-butanone]- dioximatel(1-)-N,N',N'',N''']nickel(II), Nioyl. 47. Platinum Complexes Suitable as Precursors for Synthesis in Nonaqueous Solvents. 48. Tetrakis(propanenitrile)platinum(II)Trifluoromethanesulfonate as a Suitable Intermediate in Synthetic Pt(II) Chemistry. 49. [(1,2,5,6-*)-1,5-Cyclooctadiene]dimethylplatinum(II). 50. Bis(2,2,6,6-tetramethyl-3,5 -heptanedionato)copper. 51. Lewis Base Adducts of 1,1,1,5,5,5 -Hexafluoro-2,4-pentadionato -Copper(I) Compounds. 52. Copper(II) Alkoxides. 53. Pyrazolato Copper(I) Complexes. 54. Tris(2,2,6,6-tetramethyl -3,5-heptanedionato) Yttrium. 55. Lewis Base Adducts of Uranium Triiodide and Tris[bis(trimethylsilyl)amido] uranium. Contributor Index. Subject Index. Formula Index. Chemical Abstracts Service Registry Number Index.

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v. 33 ISBN 9780471208259

内容説明

INORGANIC SYNTHESES

目次

• Chapter One SYNTHESES OF SELECTED SUPRAMOLECULES. 1. Toward Magnetic Building Blocks: Synthesis of a Planar Co(III)-cation Radical-cobalt(III) Complex of the Binucleating Ligand 1,2,4,5-Tetrakis(2-hydroxy-2-methylpropanamido)benzene. 2. A Luminescent Decanuclear Ruthenium(II) Polypyridine Complex: A Convergent Approach to a Dendritic Structure Employing the "Complexes as Metals/Complexes as Ligands" Synthetic Strategy. 3. Dodecatungstoaluminic Acid and Its Monolacunary and Mixed-Addendum Derivatives. 4. Supramolecular Complexes of BisBis(2,2'-bipyridine)osmium(II) and Ruthenium(II). 5. Binuclear Oxomolybdenum-Metalloporphyrin Complexes. 6. Iron Sandwich Polyoxoanion Compounds. 7. Dipyrryl and Porphyrinic Precursors to Supramolecular Conjugated (Porphinato)metal Arrays: Syntheses of Dipyrrylmethane and (5,15-diphenylporphinato)zinc(II). 8. Synthesis of Dodecaoxohexadecacarboxylatotetraaquo-dodecamanganese [Mn12O12(O2CR)16(H2O)4] (R = Me,Et,Ph,Cr) Complexes. 9. Use of Picolinehydroximate Complexes in Preparation of Uranyl and Lanthanide 15-Metallacrown-5: UO2(NO3)2 [15-MCCu(II)N(pic)-15] and {Eu(NO3)2[15-MCCu(II)N(pic)-15]}NO3. 10. Use of Salicyl- and Naphthoylhydroximate Complexes in Preparation of Manganese and Copper 12-Metallacrown-4 Complexes: Mn(II)(Acetate)2 [Mn(III)(salicylhydroximate)]4 and (Tetramethylammonium)2 [Cu(II)5 (naphthoylhydroximate)4]. Chapter Two USEFUL REAGENTS AND LIGANDS. 11. Homoleptic Transition Metal Acetonitrile Cations with Tetrafluoroborate or Trifluoromethanesulfonate Anions. 12. Synthesis of [MII(NCMe)6]2+ (M = V,Cr,Mn,Fe,Co,Ni) Salts of Tetra[3,5-bis(trifluoromethyl)phenyl]borate. 13. Transition Metal p-Toluenesulfonates. 14. Salts of Binuclear Iron(II) and Iron(III) Dianions [(Fe2Cl6)2- and (Fe2OCl6)2-]. 15. Tetraethylammonium-Tetrathioperrhenate Et4N(ReS4). 16. Large-Scale Synthesis of Methyltrioxorhenium (CH3ReO3). 17. 4,5-Diaminocatechol: A Useful Building Block in Synthesis of Multimetallic Complexes. 18. A Convenient Synthesis of 1,5,9-Trithiacyclododecane (S3C9H18). Chapter Three SOLID-STATE MATERIALS AND CLUSTERS. 19. Synthesis of Quaternary Selenophosphates using Molten Salt Fluxes: Rb8Hg4(Se2)2(PSe4)4, K4In2(PSe5)2(P2Se6), Rb4Ti2(P2Se7)(P2Se9)2, Rb4U4(Se)2(Se2)4(PSe4)4. 20. Hydrothermal Synthesis of Sulfosalts: Ag3AsS3, Ag3SbS3, Ag7SbS6, Cu12Sb4S13, CuInS2, FeIn2S4. 21. Open-Framework Solids of the Vanadium Oxide-Phosphate System. 22. Sulfur-Bridged Incomplete Cubane-Type Molybdenum and Tungsten Aqua Ions. 23. Sulfur-Bridged Cubane Type Mixed-Metal Clusters with Mo3MS4 (M = Fe,Co,Ni,Cu,In,Sn) and W3NiS4 Cores. 24. Molybdenum and Tungsten Clusters as Aqua Ions [M3Q4(H2O)9]4+ (M = Mo,W
• Q = S,Se) and Related Chalcogen-Rich Trinuclear Clusters. Chapter Four COMPOUNDS OF GENERAL INTEREST. 25. The Diphenylmethylenethiophosphinate (MTP) Ligand in Gold(I), Platinum(II), Lead(II), Thallium(I), and Mercury(II) Complexes, sym-Au2(MTP)2, (PPN)[Au(MTP)2], Au2Pt(MTP)4, Au2Pb(MTP)4, AuTl(MTP)4, Hg(MTP)2, Hg(MTP)2(AuCl)2, and HgIIAuI(MTP)2AuIIICl4. 26. Mesityl-gold(I) Complexes. 27. An Improved Synthesis of cis-Dithiocyanato-bis(4,4'-dicarboxy-2,2'-bpy) Ru(II) Sensitizer. 28. Dimethylsulfoxide Complexes of Platinum(II): K[PtCl3(Me2SO)], cis-[PtCl2L(Me2SO)] (L = Me2SO,MeCN), [PtCl( -Cl)(Me2SO)]2, and [Pt(Me2SO)4](CF3SO3)2. 29. Tetrasulfur-tetranitride (S4N4). 30. Hydrotris(methimazolyl)borate. 31. Arsenic(III)bromide. 32. Dichlorodioxo-bis(triphenylphosphine oxide)uranium(VI) [UO2Cl2(OPPh3)2]. 33. Chlorohydro-tris(pyrazol-1-yl)borato-bis(triphenylphosphine) ruthenium(II) {RuCl[k3-HB(pz)](PPh3)2} (pz = pyrazol-1-yl). 34. Octacarbonyl-di- -hydridodirhenium [Re2( -H)2(CO)8]. 35. Zero-Valent Binuclear Nickel Complexes. 36. Preparation of a Synthetic Ribonuclease: The Europium(III) Complex of 1-(4-nitrobenzyl)-4,7,10-Tris(carbamoylmethyl)-1,4,7,10- tetraazacyclododecane. 37. Carbonyl Halide Tungsten(II) Complexes of Tris(3,5-dimethylpyrazolyl)hydroborate. 38. A Luminescent Complex of Re(I): fac-[Re(CO)3(bpy)(py)](CF3SO3) (bpy = 2.2'-bipyridine
• py = pyridine). 39. RSi(OH)3 and RSi(NH2)3 [R = 2,6-iPr2C6H3N(SiMe3)]: Synthesis of Stable Organosilanes with Three Functional Groups. 40. Fluorination with Me3SnF: Synthesis of Cyclopentadienyl-Substituted Group 4 Metal Fluoride Complexes. 41. Seven-Coordinate [MI2(CO)3(NCMe)2], [MI2(CO)3(NCMe)(PPh3)], and Alkyne [MI2(CO)(NCMe)( 2-RC2R)2] Complexes of Molybdenum(II) and Tungsten(II). 42. Chlorothiocarbonyl-bis(triphenylphosphine)iridium(I) [IrCl(CS)(PPh3)2]. Contributor Index. Subject Index. Formula Index.

巻冊次

v. 32 ISBN 9780471249214

内容説明

The Inorganic Synthesis Series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. This new volume includes information on water-solubilizing ligands for organometallics, labile ligand complexes, and the syntheses of cluster compounds and hydrides.

目次

Chapter One LIGANDS FOR WATER-SOLUBILIZING ORGANOMETALLIC COMPOUNDS. 1. (Meta-Sulfonatophenyl)Diphenylphosphine, Sodium Salt and Its Complexes with Rhodium(I), Ruthenium(II), Iridium(1). 2. Syntheses of Water-Soluble Phosphines and Their Transition Metal Complexes. 3. Tris[Tris(Sodium m-sulfonatophenyl)phosphino] Palladium(0)-Enneahydrate. 4. Sulfonated Phosphines. 5. (S,S)-2,3-Bis[Di(m-Sodiumsulfonatophenyl)phosphino]butane-(chiraphosTS) and (S,S)-2,4-Bis[di(m-Sodiumsulfonatophenyl)-phosphinolpentane (BDPPTS). 6. 1,3,5-Triaza-7-phosphatricyclo[3.3.1.13,7]decane and Derivatives. Chapter Two BIOMIMETIC AND SPECIAL PROPERTY LIGANDS. 7. 2.2':6',2"-Terpyridine. 8. Poly(1-pyrazolyl)alkane Ligands. 9 . Tris[N-(3-tert-butyl)pyrazolyl]methane. 10. Tris[2-(1,4-Diisopropylimidazolyl)]phosphine. 11. Tris[(2-pyridyl)methyl]amine (TPA) and (+)-Bis[(2-pyridyl)-methyl]-l-(2-pyridyl)ethylamine (a-MeTPA). 12. C2-Symmetric 1,4-Diisopropyl-7-R-l,4,7-Triazacyclononanes. 13. N-(2-hydroxyethyl)-3,5-Dimethylpyrazole, a Dinuclear Copper Complex, and N-(2-p-Toluenesulfonylethyl)-3,5-dimethy-pyrazole. 14. N-(2-Mercaptoethyl)-3,5-dimethylpyrazole. 15. 1,5-Diazacyclooctane, Pendant Arm Thiolato Derivatives and [N,N'-Bis(2-Mercaptoethyl)-1,5-Diazacyclooctanato]-nickel(II). 16. Polydentate Thiolate and Selenolate Ligands, RN(CH2,CH2,S(Se)-)2, and Their Dimeric and Mononuclear Ni(II) Complexes. 17. Poly[(methylthio)methyl]borates and Representative Metal Derivative. 18. Polyaza Binucleating Ligands: OBISTREN and OBISDIEN. 19. N,N'.bis(2-hydroxybyl.thylenediamine-N,N'-diacetic acid (HBED). 20. N-Tert-Alkyl-Anilides as Bulky Ancillary Ligands. 21. 1,2-Bis(Dichlorophosphino)-1,2-Dimethylhydrazine and Alkoxy/Aryloxy Derivatives. 22. Tris[(tert-butylamino)-dimethylsilyl]methylsilane and Its Precursors. Chapter Three TRANSITION METAL COMPLEXES AND PRECURSORS. 23. Facile Synthesis of Isomerically Pure. 24. cis-Bis(benzeneacetonitrile)dichloroplatinum(II) and trans-Bis(benzeneacetonitrile)dichloroplatinum(II). 25. Platinum(II) Complexes of Dimethyl Sulfide. 26. (2,2' :6',2"-Terpyridine) Methylplatinurn(II) Chloride and (l,l0-Phenanthroline)methylchloroplatinum(II). 27. (N,N-Chelate)(olefin)platinum(0) Complexes. 28. Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes. 29. 2,4-Pentanedionatogold(I) Complexes and 2,4-Pentanedionatothallium. 30. Tetrakis(Pyridine)SiIver(2 + )Peroxydisulfate. 31. One-Pot Synthesis of Tetrahydronium Tris(4,4'-Dicarboxylato-2,2'-Bipyridine)ruthenium(II) Dihydrate. 32. Trichloro[2,2' :6,2"-Terpyridine]ruthenium(III) and Phosphine Ligand Derivatives. 33. Monomeric Tetrahydrofuran-Stabilized Molybdenum(III) Halides. 34. Facial Molybdenum(lI1) Triamine Complexes. 35. High-Valent Mono-(5-Pentamethylcyclopentadienyl)vanadium and Molybdenum Complexes. 36. Monoindenyltrichloride Complexes of Titanium(IV), Zirconium(IV), and Hafnium(IV). 37. Labile Copper(I) Chloride Complexes: Preparation and Handling. Chapter Four MAIN GROUP AND TRANSITION METAL CLUSTER COMPOUNDS. 38. 7,8-Dicarbaundecaborane(13). 39. Borazine, Polyborazylene, B-Vinylborazine and Poly(B-Vinylborazine). 40. Transition Metal Complexes of the Lacunary Heteropolytungstate, [P2W17O61] 10-. 41. Bis(Triphenylphosphorany1idene)A mmonium -Carbonyl-1kC:2kC-Decacarbonyl-1k3C,2k3,3k4C--Hydrido-1k:2k-triangubTriruthenate(1-). 42. Dipotassium Undecacarbonyl Trimetallate(2-) Clusters, K2[M3(CO)11] (M = Ru, Os). 43. [PPN]2[Ru3(CO)11] and [PPN]2[OS3(CO)11], -Nitrido-Bis(Triphenylphosphorus) (1 +) Undecacarbonyltriruthenate (2 -) and Undecacarbonyltriosmate(2 -). 44. Platinum-Ruthenium Carbonyl Cluster Complexes. 45. Tri(-carbonyl)nonacarbonyltetrarhodiu. 46. High Nuclearity Hydridodecaruthenium Clusters. Chapter Five MAIN GROUP AND TRANSITION METAL HYDRLDES. 47. Dichlorodihydro(N,N,N',N,-Tetraethyl-1,2-ethanediamine-N,N')silicon. 48. Tricarbonyl(hydrido)[1,2-bis(diphenylphosphino)ethane]-manganese as Precursor to Labile Site Derivatives. 49. Pentahydridobis(tricyclohexylphosphine)iridium(V) and trihydridotris (triphenylphosphine)iridium(III). Chapter Six TITANIUM(1II) CHLORIDE. (A Correction to Inorganic Syntheses, Vol. 24, pp. 181 (1986). 50. An Active Form of Titanium(II1) Chloride. Contributor Index. Subject Index. Formula Index. Chemical Abstracts Service Registry Number Index.

巻冊次

collective index for v. 1-30 ISBN 9780471305071

内容説明

Chemistry under extreme conditions (e.g., high temperature) offers the possibility to use elements for synthesis in one of their highest reactive forms, the atomic state. This book describes various experimental techniques that are not routinely employed by synthetic, organic, inorganic, and polymer chemists. It covers high temperature/high pressure reaction conditions, the use of supercritical media, and sonochemistry.

巻冊次

v. 26 ISBN 9780471504856

内容説明

This book identifies important inorganic compounds, and describes foolproof methods for their preparation. Compounds are arranged by chemical relation, and within each chapter according to the columns of the periodic table. Each product description includes a concise and critical summary of the available procedures for synthesis, and an estimate of the time required for the process. It gives clear laboratory directions and carefully outlines any potential hazards associated with the synthesis. The usefulness of the resultant compound and how to judge its purity is discussed. The text will benefit biologists, chemists and biochemists.

目次

• Compounds of the main group elements and the lanthanides
• mononuclear transition metal complexes
• complexes with weakly bonded anions
• mononuclear transition metal complexes
• metalocyclic complexes
• polynuclear transition metal complexes
• solid state.

巻冊次

v. 27 ISBN 9780471509769

内容説明

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

目次

Transition Metal Polyhydride Complexes. Transition Metal Chalcogenide Complexes. Early Transition Metal Polyoxoanions. Lanthanide and Actinide Complexes. Transition Metal Cluster Complexes. Phosphorus Complexes and Compounds. Transition Metal Complexes of Biological Interest. Miscellaneous Transition Metal Complexes. Ligands and Other Main Group Compounds. Sources of Chemicals and Equipment. Index of Contributors. Subject Index. Formula Index.

巻冊次

v. 29 ISBN 9780471544708

内容説明

This volume contains information on inorganic polymer syntheses and the preparation of inorganic ring systems, syntheses used in the development of pharmacologically-active inorganic compounds and small-molecule co-ordination complexes, as well as transition organometallic compounds.

目次

• Main group compounds - general
• boron compounds
• transition metal co-ordination compounds
• transition metal organometallics and ligands
• cluster and cage compounds containing transition metals.

巻冊次

v. 25 ISBN 9780471618744

内容説明

Presented here is a compilation of current techniques and ideas in inorganic synthetic chemistry. It includes inorganic polymer syntheses and preparation of inorganic ring systems, syntheses used in the development of pharmacologically active inorganic compounds, and small-molecule coordination complexes and related compounds. The volume also contains a section on transition organometallic compounds, including species with metal-metal bonds and cluster molecules. All syntheses given here have been tested. The text will be of benefit to graduate students and inorganic synthetic chemists. 07 Series: Inorganic Syntheses

目次

Partial table of contents: MAIN GROUP RING SYSTEMS AND RELATED COMPOUNDS. Organocyclophosphanes. Binary Cyclic Nitrogen-Sulfur Anions. INORGANIC POLYMER SYSTEMS. Organosilane High Polymers: Poly(methylphenylsilylene). Organosilicon Derivatives of Cyclic and High Polymeric Phosphazenes. COMPOUNDS OF PHARMACOLOGICAL INTEREST. Boron Analogs of Amino Acids. cis-Diammineplatinum alpha-Pyridone Blue. METAL COMPOUNDS, COMPLEXES, AND LIGANDS. (Benzenethiolato)tributylin. The Ammonium Chloride Route to Anhydrous Rare Earth Chlorides--The Example of YCl3. TRANSITION METAL ORGANOMETALLIC COMPOUNDS. Dinuclear Phosphido and Arsenido Derivatives of Molybdenum. Mixed Cobalt-Ruthenium Dodecacarbonyl Clusters: Co3RuH(CO)12. Index of Contributors. Subject Index. Formula Index.

巻冊次

v. 34 ISBN 9780471647508

内容説明

This series provides inorganic chemists with detailed and foolproof procedures for the preparation of important and timely compounds. Volume 34 continues to report such procedures with an up-to-date selection of contributions by internationally-recognized researchers, including the following:

目次

• Chapter One MAIN GROUP COMPOUNDS. 1. Diborane(4) Compounds. 2. Sodium Tetrakis(3,5-bis(trifluoromethyl)phenyl)borate, Na[B(3,5-(CF3)2C6H3)4]. 3. Anionic Tris- and Bis(diphenylphosphinomethyl)borates. 4. Six-Coordinate Aluminum Cations Based on Salen Ligands. 5. Tabular -Alumina. 6. Para-Substituted Aryl Isocyanides. 7. Unsymmetric Tripod Ligands Related to Tris(pyrazol-1-yl)methane. 8. Difluorotriphenylarsenic(V), AsF2Ph3. 9. Tetramethylammonium Salts of Superoxide and Peroxynitrite. 10. Tellurium-Nitrogen Compounds. Chapter Two ORGANOMETALLIC AND COORDINATION COMPLEXES. 11. Addition Compounds of Dibromodioxomolybdenum(VI). 12. Oxorhenium(V) Oxazoline Complexes for Oxygen Atom Transfer. 13. Allyl and Dienyl Complexes of Ruthenium. 14. Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) Chloride, [Ru(4,7-Ph2phen)3]Cl2. 15. Metal Complexes of a Diimino(tetracyano)pyrrolizinide Ligand Derived from Tetracyanoethylene. 16. Cationic Pt(II) Complexes of Tridentate Amine Ligands. 17. Platinum(II) Complexes of Propanone Oxime. 18. Trifluoromethanesulfonatosilver(I) Derivatives. 19. Pentakis(tetrahydrofuran)dicadmium Tetrakis(tetrafluoroborate), [Cd2(THF)5][BF4]4. 20. Di(-chloro)bis{chlorodioxobis(tetrahydrofuran)uranium(VI)}, {UO2Cl2(THF)2}2. Chapter Three TRANSITION METAL CARBONYL COMPOUNDS. 21. Hexacarbonylvanadate(1-) and Hexacarbonylvanadium(0). 22. Tricarbonyltris(pyridine)molybdenum(0) and Its Use as a Mo(0) Source for Allylmolybdenum(II) Complexes. 23. A Tungsten(0)-Fullerene-60 Derivative. 24. Dodecacarbonyltriruthenium, Ru3(CO)12. 25. Dicarbonylbis(hexafluoroacetylacetonato)ruthenium, Ru(CO)2(hfac)2. 26. Carbonyl Complexes of Ruthenium(II) from Dimethylformamide. 27. Rhodium(I) and Iridium(I) Carbonyl Complexes. 28. Useful Mononuclear Rhodium(I) and Iridium(I) Compounds. Chapter Four CYANIDE COMPOUNDS. 29. Hexacyanometallates as Templates for Discrete Pentanuclear and Heptanuclear Bimetallic Clusters. 30. A Mixed-Valence Heptanuclear Iron Complex. 31. Potassium Hexacyanochromate(III) and Its 13C-Enriched Analog. 32. Two Polynuclear Nickel(II)-Hexacyanochromate(III) Complexes. 33. Trimethyltriazacyclononanechromium(III) Complexes and a Chromium(III)-Nickel(II)-Cyanide Cluster with a Face-Centered Cubic Geometry. 34. Cyano-Bridged M(II)9M(V)6 Molecular Clusters, M(II) = Mn,Co,Ni
• M(V) = Mo,W. 35. Cyanometal-Substituted Derivatives of the Fe4S4 Cluster Core. 36. Tricyanometalate Building Blocks and Organometallic Cyanide Cages. 37. Phosphine Ligand Derivatives of Diamond-Shaped, Cyanide-Bridged Iron(II)-Copper(I) Complexes. 38. Cyanide-Bridged Iron(II)-M(II) Molecular Squares, M(II) = Fe(II), Co(II),Cu(II). 39. Poly{(2,2'-(bipyridine)(triphenylphosphine)bis(dicyanocopper(I)}, {(CuCN)2(bpy)(PPh3)}n. Chapter Five CLUSTER AND POLYNUCLEAR COMPOUNDS. 40. A Tetranuclear Lanthanide-Hydroxo Complex Featuring the Cubane-like [Ln4(3-OH)4]8+ Cluster Core, [Nd4(3-OH)4(H2O)10 (alanine)6] [ClO4]8. 41. Tetradecachlorohexatantalum Octahydrate, Ta6Cl18.8H2O. 42. Polyoxomolybdate Clusters: Giant Wheels and Balls. 43. Tetrakis{n6-1-isopropyl-4-methylbenzene)ruthenium(II) tetraoxomolybdate(VI)}. 44. Diruthenapenta- and Diruthenahexaboranes. 45. Mixed-Metal Clusters of Iridium with Ruthenium and Osmium. 46. Tri- and Hexaruthenium Carbonyl Clusters. 47. Silica-Mediated Synthesis of Os3(CO)10(-H)(-OH). 48. Efficient Base- and Silica-Mediated Syntheses of Osmium Cluster Anions from -{Os(CO)3Cl2}2. 49. Triosmium Complexes of Fullerene-60. 50. Triphenylphosphine-Stabilized Gold Nanoparticles. Contributor Index. Subject Index. Formula Index.

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v. 35 ISBN 9780471682554

内容説明

The Inorganic Syntheses series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. Includes complete, up-to-date procedures involving important inorganic substances Contains subject, contributor, and formula indexes

目次

• Preface. Contributors. Dedication. Notice to Contributors and Checkers. Toxic Substances and Laboratory Hazards. Chapter One COMPLEXES OF BULKY ss-DIKETIMINATE LIGANDS. 1. Introduction. 2. ss-Diketiminate Precursors HLMe,Me3 and TlLMe,Me3 (LMe,Me3 = 2,4-Bis-(Mesitylimido)Pentyl). 3. ss-Diketiminate Precursors LMe,iPr2H, [LMe,iPr2Li]x, and [LtBu,iPr2K]x (LMe,iPr2 = 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl
• LtBu,iPr2 = 2,2,6,6- Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido)Heptyl). 4. ss-Diketiminate Precursors LtBu,iPr2H and LtBu,iPr2Li(THF) (LtBu,iPr2=2,2,6,6-Tetramethyl-3,5- Bis-(2,6-Diisopropylphenylimido)Heptyl). 5. Scandium Trichloride Tris(Tetrahydrofuran) and ss-Diketiminate-Supported Scandium Chloride Complexes. 6. ss-Diketiminate-Supported Titanium and Vanadium Dichloride Complexes. 7. ss-Diketiminate-Supported Vanadium and Chromium Chloride Complexes. 8. ss-Diketiminate-Supported Manganese and Zinc Complexes. 9. Iron 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride (LMe,iPr2FeCl). 10. Iron 2,2,6,6-Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido)Heptyl Chloride (LtBu,iPr2FeCl). 11. Cobalt 2,2,6,6-Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido) Heptyl Chloride (LtBu,iPr2CoCl). 12. ss-Diketiminate-Supported Nickel(II) and Nickel(I) Complexes of LMe,Me3 (LMe,Me3 = 2,4-Bis-(Mesitylimido)Pentyl). 13. Nickel 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride Dimer, [LMe,iPr2Ni(-Cl)]2. 14. Bis[Copper 2,4-Bis-(2,4,6-Trimethylphenylimido)Pentyl] Toluene, (LMe,Me3Cu)2(-n2:n2-C7H8). 15. Copper 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride (LMe,iPr2CuCl). Chapter Two BORON CLUSTER COMPOUNDS. 16. Salts of Dodecamethylcarba-closo-Dodecaborate(-) Anion, CB11Me12, and the Radical Dodecamethylcarba-closo-Dodecaboranyl, CB11Me12. 17. Cesium Dodecahydroxy-closo-Dodecaborate, Cs2[B12(OH)12]. Chapter Three COORDINATION COMPOUNDS. 18. Pentaaquanitrosylchromium Sulfate. 19. The Tetradentate Bispidine Ligand Dimethyl-(3,7-Dimethyl-9-oxo-2,4-bis(2-pyridyl)-3,7-Diazabicyclo[3.3.1]nonane)-1, 5-dicarboxylate and Its Copper(ll) Complex. 20. Tris(2-Picolinyl)Methane and Its Copper(I) Complex. Chapter Four CARBENE LIGANDS AND COMPLEXES. 21. 1,3-Dialkyl-Imidazole-2-Ylidenes. 22. A Chelating Rhodium N-Heterocyclic Carbene Complex by Transmetallation from a Silver-NHC Intermediate. 23. Rhodium and Iridium N-Heterocyclic Carbene Complexes from Imidazolium Carboxylates. Chapter Five FUNCTIONAL LIGANDS AND COMPLEXES. 24. N-tert-Butyl ortho-Aminophenol, ortho-Iminoquinone, and a Zirconium(IV) bis(Aminophenolate) Complex. 25. Synthesis of the Water-Soluble Bidentate (P, N) Ligand PTN(Me) (PTN(Me) = 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane). 26. Synthesis of Metal-Organic Frameworks: MOF-5 and MOF-177. Chapter Six ORGANOMETALLIC REAGENTS. 27. Tricarbonyl 1,3,5-Trimethyl-1,3,5-Triazacyclohexane Complexes of Chromium(0), Molybdenum(0), and Tungsten(0) [M(CO)3(Me3TACH) (M = Cr, Mo, W)]. 28. Manganese Tricarbonyl Transfer (MTT) Agents. 29. Bis(1,5-Cyclooctadiene)Nickel(0). 30. Sodium (n5-Cyclopentadienyl)Tris(Dimethylphosphito-P) Cobaltate(III), Na[(C5H5)Co{P(O)(OMe)2}3]. Chapter Seven BIO-INSPIRED IRON AND NICKEL COMPLEXES. 31. Iron-Cyanocarbonyl Complexes [PPN][Fe(CO)4(CN)] and [PPN][FeBr(CO)3(CN)2]. 32. Nickel Complexes of Bis(Diethylphosphinomethyl) Methylamine. 33. Monomeric Iron(II) Complexes Having Two Sterically Hindered Arylthiolates. 34 (1,3-Propanedithiolato)-Hexacarbonyldiiron and Cyanide Derivatives. Chapter Eight RUTHENIUM COMPLEXES. 35. Ruthenium(II)-Chlorido Complexes of Dimethylsulfoxide. 36. Synthesis of Chloride-Free Ruthenium(II) Hexaaqua Tosylate, [Ru(H2O)6]tos2. 37. Basic Ruthenium Acetate and Mixed Valence Derivatives. 38. Di--Chloro(Ethylbenzoate)Diruthenium(II), [(n6-etb)RuCl2]2. Chapter Nine IRIDIUM COMPLEXES. 39. The Diphosphine tfepma and its Diiridium Complex Ir20,II(tfepma)3Cl2. 40. Heteroleptic Cyclometalated Iridium(III) Complexes. 41. Oxygen and Carbon Bound Acetylacetonato Iridium(III) Complexes. Contributor Index. Subject Index. Formula Index.

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v. 23 ISBN 9780471818731

内容説明

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

目次

• Organometallic Compounds
• Compounds of Biological Interest
• Stereoisomers
• Bridge and Cluster Compoundes
• Unusual Ligands and Compounds.

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v. 24 ISBN 9780471834410

内容説明

Preparative chemistry is the heart of chemistry. The goal of "Inorganic Syntheses" is to provide both the student and the practising chemist with safe and reliable methods for preparing useful compounds. Divided into five parts, Volume 24 covers synthetic methods for fluorine-containing compounds, main group compounds, transition metal organometallic compounds, transition metal compounds complexes. The aim of this book is to serve as a valuable reference containing the precursors of yet undiscovered compounds and to demonstrate practical techniques to the student.

目次

• Fluorine-containing Compounds
• Main Group Compounds
• Transition Metal Organometallic Compounds
• Transition Metal Compounds and Complexes
• Trifluoromethanesulphonates and Trifluoromethanesulphonato-O Complexes.

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v. 22 ISBN 9780471888871

内容説明

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

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v. 36 ISBN 9781118744871

内容説明

This volume of Inorganic Syntheses spans the preparations of wide range of important inorganic, organometallic and solid-state compounds. The volume is divided into 6 chapters. The first chapter contains the syntheses of some key early transition metal halide clusters and the very useful mononuclear molybdenum(III) synthon, MoCl3(THF)3. Chapter 2 covers the synthesis of a number of cyclopentadienyl compounds, including a novel route to sodium and potassium cyclopentadienide, MC5H5. Chapter 3 details synthetic procedures for a range of metal-metal bonded compounds, including several with metal-metal multiple bonds. Chapter 4 contains procedures for a range of early and late transition metal compounds, each a useful synthon for further synthetic elaboration. Chapter 5 deals with the synthesis of a number of main group compounds and ligands, while Chapter 6 covers teaching laboratory experiments.

目次

Preface v Dedication vii Notice to Contributors and Checkers xv Toxic Substances and Laboratory Hazards xvii Chapter One TRANSITION METAL HALIDE COMPOUNDS 1 1. Octahedral Hexatantalum Halide Clusters 1 A. Tetradecachlorohexatantalum Octahydrate 3 B. Tetradecabromohexatantalum Octahydrate 4 C. Tetrakis(benzyltributylammonium) Octadecachlorohexatantalate 5 2. Octahedral Hexamolybdenum Halide Clusters 8 A. Tetradecachlorohexamolybdate Hexahydrate (Chloromolybdic Acid) 10 B. Hexamolybdenum Dodecachloride 12 3. Ether Complexes of Molybdenum(III) and Molybdenum(IV) Chlorides 15 A. Tetrachlorobis(diethyl ether)molybdenum(IV) 16 B. Trichlorotris(tetrahydrofuran)molybdenum(III) 17 4. Octahedral Hexatungsten Halide Clusters 19 A. Bis(hydroxonium) Tetradecachlorohexatungstate Heptahydrate (Chlorotungstic Acid) 21 B. Hexatungsten Dodecachloride 22 5. Trinuclear Tungsten Halide Clusters 24 A. Tritungsten Decachloride 26 B. Trisodium Tridecachlorotritungstate 27 C. Tris(benzyltributylammonium) Tridecachlorotritungstate 28 6. Crystalline and Amorphous Forms of Tungsten Tetrachloride 30 A. Crystalline Tungsten Tetrachloride by Solid-State Reduction 32 B. Amorphous Tungsten Tetrachloride by Solution-Phase Reduction 33 Chapter Two CYCLOPENTADIENYL COMPOUNDS 35 7. Sodium and Potassium Cyclopentadienide 35 A. Sodium Cyclopentadienide 36 B. Potassium Cyclopentadienide 37 8. (Pentafluorophenyl)cyclopentadiene and its Sodium Salt 38 A. (Pentafluorophenyl)cyclopentadiene 39 B. Sodium (Pentafluorophenyl)cyclopentadienide 41 9. Bis( 5-pentamethylcyclopentadienyl) Complexes of Scandium 42 A. Bis( 5-pentamethylcyclopentadienyl)chloroscandium 43 B. Bis( 5-pentamethylcyclopentadienyl)methylscandium 44 C. Bis( 5-pentamethylcyclopentadienyl)phenylscandium 45 D. Bis( 5-pentamethylcyclopentadienyl)(o-tolyl)scandium 46 10. Bis( 5-pentamethylcyclopentadienyl) Complexes of Titanium, Zirconium, and Hafnium 47 A. Bis( 5-pentamethylcyclopentadienyl)dichlorotitanium(IV) 47 B. Bis( 5-pentamethylcyclopentadienyl)dichlorozirconium(IV) 49 C. Bis( 5-pentamethylcyclopentadienyl)dichlorohafnium(IV)50 11. Bis( 5-pentamethylcyclopentadienyl) Complexes of Niobium and Tantalum 52 A. Bis( 5-pentamethylcyclopentadienyl)dichlorotantalum(IV) 53 B. Bis( 5-pentamethylcyclopentadienyl)dichloroniobium(IV) 55 12. Bis( 5-pentamethylcyclopentadienyl) Complexes of Molybdenum 58 A. Bis(pentamethylcyclopentadienyl)dichloromolybdenum(IV) 59 B. Bis(pentamethylcyclopentadienyl)dihydridomolybdenum(IV) 61 13. ( 5-Cyclopentadienyl)tricarbonylmanganese(I) Complexes 62 A. ( 5-Cyclopentadienyl)tricarbonylmanganese(I) 63 B. ( 5-Pentamethylcyclopentadienyl)tricarbonylmanganese(I) 63 14. 1,10-Diaminoferrocene 65 A. 1,10-Dilithioferrocene N,N,N0,N0-Tetramethylethylenediamine 66 B. 1,10-Dibromoferrocene 67 C. One-Pot Preparation of 1,10-Dibromoferrocene from Ferrocene 68 D. 1,10-Diaminoferrocene 69 E. 1,10-Diaminoferrocenium Hexafluorophosphate 70 F. 1,10-Diaminoferrocenium Triflate 71 15. Mono( 5-pentamethylcyclopentadienyl) Complexes of Osmium 72 A. Bromoosmic Acid 74 B. Bis( 5-pentamethylcyclopentadienyl)tetrabromodiosmium(III) 75 C. ( 5-Pentamethylcyclopentadienyl)(1,5-cyclooctadiene)-bromoosmium(II) 76 Chapter Three COMPOUNDS WITH METAL-METAL BONDS 78 16. Tetra(acetato)dimolybdenum(II) 78 17. Supramolecular Arrays Based on Dimolybdenum Building Blocks 81 A. Tetrakis(N,N0-di-p-anisylformamidinato)dimolybdenum(II) 84 B. Tris(N,N0-di-p-anisylformamidinato)di(chloro)-dimolybdenum(II,III) 86 C. cis-Bis(N,N0-di-p-anisylformamidinato)tetrakis(acetonitrile)-dimolybdenum(II) Bis(tetrafluoroborate) 87 D. ( 2-Succinato)bis[tris(N,N0-di-p-anisylformamidinato)-dimolybdenum(II)] 88 E. ( 2- 2, 2-Molybdato)bis[tris(N,N0-di-p-anisylformamidinato)-dimolybdenum(II)] 89 F. ( 2-N,N0-Diphenylterephthaloyldiamidato)bis[tris(N,N0-di-panisylformamidinato) dimolybdenum(II)] 90 G. Molecular Propeller: ( 3-Trimesate)tris[tris(N,N0-di-panisylformamidinato) dimolybdenum(II)] 91 H. Molecular Loop: closo-Bis( 2-malonato)bis[bis(N,N0-di-panisylformamidinato) dimolybdenum(II)] 92 I. Molecular Triangle: closo-Tris( 2-eq,eq-1,4-cyclohexanedicarboxylato) tris[bis(N,N0-di-p-anisylformamidinato)-dimolybdenum(II)]92 J. Molecular Square: closo-Tetrakis( 2-oxalato)tetrakis[bis(N,N0-di-p-anisylformamidinato)dimolybdenum(II)] 93 K. Molecular Cage: closo-Tetrakis( 3-trimesate)hexakis[bis(N,N0-di-p-anisylformamidinato)dimolybdenum(II)] 94 18. Dimolybdenum and Ditungsten Hexa(alkoxides) 95 A. Hexa(tert-butoxy)dimolybdenum(III) 96 B. Hexakis(2-trifluoromethyl-2-propoxy)dimolybdenum(III) 97 C. Sodium Heptachloropentakis(tetrahydrofuran)ditungstate(III) 98 D. Hexa(tert-butoxy)ditungsten(III) 99 E. Hexakis(2-trifluoromethyl-2-propoxy)ditungsten(III) 100 19. Linear Trichromium, Tricobalt, Trinickel, and Tricopper Complexes of 2,20-Dipyridylamide 102 A. Dichlorotetrakis(2,20-dipyridylamido)trichromium(II) 103 B. Dichlorotetrakis(2,20-dipyridylamido)tricobalt(II) 104 C. Dichlorotetrakis(2,20-dipyridylamido)trinickel(II) 105 D. Dichlorotetrakis(2,20-dipyridylamido)tricopper(II) 106 E. Bis(acetonitrile)tetrakis(2,20-dipyridylamido)trichromium(II) Bis(hexafluorophosphate) 107 F. Bis(acetonitrile)tetrakis(2,20-dipyridylamido)tricobalt(II) Bis(hexafluorophosphate) 108 G. Bis(acetonitrile)tetrakis(2,20-dipyridylamido)trinickel(II) Bis(hexafluorophosphate) 108 20. Bis(tetrabutylammonium) Octachloroditechnetate(III) 110 A. Tetrabutylammonium Pertechnetate(VII) 111 B. Tetrabutylammonium Oxotetrachlorotechnetate(V) 112 C. Bis(tetrabutylammonium) Octachloroditechnetate(III) 112 21. Diruthenium Formamidinato Complexes 114 A. Chlorotris(acetato)(N,N0-di-2,6-xylylformamidinato)-diruthenium(II,III) 115 B. trans-Chlorobis(acetato)bis(N,N0-di-2,6-xylylformamidinato)-diruthenium(II,III) 117 C. cis-Chlorobis(acetato)bis(N,N0-di-p-anisylformamidinato)-diruthenium(II,III) 118 D. Chloro(acetato)tris(N,N0-di-p-anisylformamidinato)-diruthenium(II,III) 119 E. Chlorotetrakis(N,N0-di-p-anisylformamidinato)-diruthenium(II,III) 120 22. Heptacarbonyl(disulfido)dimanganese(I) 122 23. Di(carbido)tetracosa(carbonyl)decaruthenate(2-) Salts 124 A. Calcium Di(carbido)tetracosa(carbonyl)decaruthenate(2-) 124 B. Bis[bis(triphenylphosphoranylidene)ammonium] Di(carbido)tetracosa(carbonyl)decaruthenate(2-) 125 Chapter Four GENERAL TRANSITION METAL COMPOUNDS 127 24. Bis(1,2-bis(dimethylphosphano)ethane)tricarbonyltitanium(0) and Hexacarbonyltitanate(2-) 127 A. Bis(1,2-bis(dimethylphosphano)ethane)-tricarbonyltitanium(0) 129 B. Bis[18-crown-6)(acetonitrile)potassium] Hexacarbonyltitanate(2-) 131 25. Tungsten Benzylidyne Complexes 134 A. Trichloro(1,2-dimethoxyethane)benzylidynetungsten(VI) 135 B. Chloro Bis[1,2-bis(diphenylphosphino)ethane]-benzylidynetungsten(IV) 136 26. Tungsten Oxytetrachloride and (Acetonitrile)tetrachlorotungsten Imido Complexes 138 A. Tungsten Oxytetrachloride 139 B. (Acetonitrile)tetrachloro(phenylimido)tungsten(VI) 140 C. (Acetonitrile)tetrachloro(2-propylimido)tungsten(VI) 141 D. (Acetonitrile)tetrachloro(2-propenylimido)tungsten(VI) 142 27. Tungsten Oxytetrachloride and Several Tungstate Salts 143 A. Tungsten Oxytetrachloride 144 B. Bis(tetrabutylammonium) Hexapolytungstate 145 C. Di(cetylpyridinium) Peroxoditungstate 146 D. Bis(tetrabutylammonium) Phenylphosphonatodiperoxotungstate 147 28. Bromotricarbonyldi(pyridine)manganese(I) 148 29. Bis(tetraethylammonium) fac-Tribromotricarbonylrhenate(I) and -Technetate(I) 149 A. Bis(tetraethylammonium) fac-Tribromotricarbonylrhenate(I) 151 B. Bis(tetraethylammonium) fac-Trichlorotricarbonyltechnetate(I) 152 30. Methyl(oxo)rhenium(V) Complexes with Chelating Ligands 155 A. Methyl(oxo)(1,2-ethanedithiolato)rhenium(V) Dimer 156 B. Methyl(oxo)bis(2-oxyquinoline)rhenium(V) 157 C. Methyl(oxo)(2,20-thiodiacetato)(triphenylphosphine)-rhenium(V) 158 31. Hexahydridoferrate(II) Salts 160 A. Tetrakis[bromobis(tetrahydrofuran)magnesium] Hexahydridoferrate(II) 161 B. Tetrakis[2-methyl-2-propoxomagnesium] Hexahydridoferrate(II) 163 32. Tris(allyl)iridium and -Rhodium 165 A. Allyllithium 166 B. mer-Trichlorotris(tetrahydrothiophene)iridium(III) 166 C. mer-Trichlorotris(tetrahydrothiophene)rhodium(III) 167 D. Tris(allyl)iridium(III) 168 E. Tris(allyl)rhodium(III) 170 33. Trinuclear Palladium(II) Acetate 171 Chapter Five MAIN GROUP COMPOUNDS AND LIGANDS 174 34. Monocarbaborane Anions with 10 or 12 Vertices 174 A. Tetraethylammonium arachno-6-Carba-decaboranate(14) 176 B. Tetraethylammonium closo-2-Carba-decaboranate(10) 177 C. Tetraethylammonium closo-1-Carba-decaboranate(10) 178 D. Tetraethylammonium closo-1-Carba-dodecaboranate(12) 179 E. Tetraethylammonium nido-6-Phenyl-6-carbadecaboranate(12) 180 F. Tetraethylammonium closo-2-Phenyl-2-carbadecaboranate(10) 181 G. Tetraethylammonium closo-1-Phenyl-1-carbadecaboranate(10) 182 H. Tetraethylammonium closo-1-Phenyl-1-carbadodecaboranate(12) 183 35. Tetrakis(5-tert-butyl-2-hydroxyphenyl)ethene 186 A. 5,50-Di-tert-butyl-2,20-dimethoxybenzophenone 187 B. Titanium Trichloride 1,2-Dimethoxyethane (1:1.5) 189 C. Tetrakis(5-tert-butyl-2-methoxyphenyl)ethene 189 D. Tetrakis(5-tert-butyl-2-hydroxyphenyl)ethene 192 36. Electrochemical Synthesis of Tetraethylammonium Tetrathiooxalate 195 37. Mid-Infrared Emitting Lead Selenide Nanocrystal Quantum Dots 198 A. Lead Selenide NQDs Emitting at 2.5 m (0.50 eV) 199 B. Lead Selenide NQDs Emitting at 2.8 m (0.44 eV) 200 C. Lead Selenide NQDs Emitting at 3.3 m (0.38 eV) 201 D. Lead Selenide NQDs Emitting at 3.5 m (0.35 eV) 201 Chapter Six TEACHING LABORATORY EXPERIMENTS 203 38. Tetra(acetato)dichromium(II) Dihydrate 203 39. Keggin Structure Polyoxometalates 210 A. Tri(ammonium) 12-Molybdophosphate 211 B. 12-Tungstosilicic Acid 212 C. 12-Tungstophosphoric Acid 214 D. 12-Molybdophosphoric Acid 215 40. Quadruply Metal-Metal Bonded Complexes of Rhenium(III) 217 A. Tetrabutylammonium Perrhenate(VII) 218 B. Bis(tetrabutylammonium) Octachlorodirhenate(III) 219 C. Tetra(acetato)dichlorodirhenium(III) 221 41. Bis[bis(triphenylphosphoranylidene)ammonium] Undecacarbonyltriferrate(2

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v. 37 ISBN 9781119477730

内容説明

The newest volume in the authoritative Inorganic Syntheses book series provides users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely inorganic and organometallic compounds that can be used in reactions to develop new materials, drug targets, and bio-inspired chemical entities.

目次

• Note to Contributors and Checkers xv Toxic Substances and Laboratory Hazards xvii Preface xix Chapter One DIVALENT MANGANESE, IRON, AND COBALT BIS(TRIMETHYLSILYL)AMIDO DERIVATIVES AND THEIR TETRAHYDROFURAN COMPLEXES 1 1. Introduction 1 2. Bis{bis(trimethylsilyl)amido}iron(II) dimer: [Fe{N(SiMe3)2}2]2 4 A. Bis{bis(trimethylsilyl)amido}iron(II) dimer: [Fe{N(SiMe3)2}2]2 5 3. Bis{bis(trimethylsilyl)amido}cobalt(II) dimer, [Co{N(SiMe3)2}2]2,and bis{bis(trimethylsilyl)amido}(tetrahydrofuran)cobalt(II),Co{N(SiMe3)2}2(THF) 7 A. Bis{bis(trimethylsilyl)amido}cobalt(II) dimer: [Co{N(SiMe3)2}2]2 . 8 B. Bis{bis(trimethylsilyl)amido}(tetrahydrofuran)cobalt(II): Co{N(SiMe3)2}2(THF) 9 4. Bis{bis(trimethylsilyl)amido}manganese(II) dimer, [Mn{N(SiMe3)2}2]2, and its THF complexes Mn{N(SiMe3)2}2(THF) and Mn{N(SiMe3)2}2(THF)2 10 A. Bis{bis(trimethylsilyl)amido}(tetrahydrofuran)manganese(II),Mn{N(SiMe3)2}2(THF), and bis{bis(trimethylsilyl)amido} manganese(II) dimer, [Mn{N(SiMe3)2}2]2 11 B. Bis{bis(trimethylsilyl)amido}bis(tetrahydrofuran)manganese(II) 12 C. An alternative synthesis of Mn{N(SiMe3)2}2(THF) and [Mn{N(SiMe3)2}2]2 12 Chapter Two CALCIUM, STRONTIUM, GERMANIUM, TIN, AND LEAD BIS(TRIMETHYLSILYL)AMIDO DERIVATIVES AND 2,2,6,6- TETRAMETHYLPIPERIDIDO AND N-ISOPROPYLPHENYLAMIDO DERVATIVES OF POTASSIUM AND CALCIUM 15 1. Introduction 15 2. Potassium (2,2,6,6-tetramethylpiperidide), bis(2,2,6,6- tetramethylpiperidido) (N,N,N',N' -tetramethylethylenediamine)calcium(II), potassium (N-isopropylanilido), and bis(N-isopropylanilido) Tris (tetrahydrofuran)calcium(II) 18 A. Potassium 2,2,6,6-tetramethylpiperidide 19 B. Diiodotetrakis(tetrahydrofuran)calcium(II) 20 C. Bis(2,2,6,6-tetramethylpiperidido)(N,N,N',N'- tetramethylethylenediamine)calcium(II) 20 D. Potassium N-{isopropyl(phenyl)amide} (Potassium N-isopropylanilide) 21 E. Bis{<!-- -->N-isopropyl(phenyl)amido}tris(tetrahydrofuran)calcium(II) 22 F. Bis[{bis(tetrahydrofuran)potassium}bis{ -N(isopropyl)(phenyl) amido}]calcium(II) 22 3. Bis{bis(trimethylsilyl)amido}calcium(II) dimer, [Ca{N(SiMe3)2}2]2, and bis {bis(trimethylsilyl)amido}strontium(II) dimer, [Sr{N(SiMe3)2}2]2 24 A. Bis{bis(trimethylsilyl)amido}calcium(II) dimer, [Ca{N(SiMe3)2}2]2,and bis{bis(trimethylsilyl)amido}strontium(II) dimer, [Sr{N(SiMe3)2}2]2 25 4. Divalent Group 14 metal bis(trimethylsilylamides), M{N(SiMe3)2}2 (M = Ge, Sn, Pb) 26 A. Bis{bis(trimethylsilyl)amido}germanium(II), Ge{N(SiMe3)2}2 27 B. Bis{bis(trimethylsilyl)amido}tin(II), Sn{N(SiMe3)2}2 28 C. Bis{bis(trimethylsilyl)amido}lead(II), Pb{N(SiMe3)2}2 29 Chapter Three COMPOUNDS WITH Zn-Zn AND Mg-Mg BONDS: DECAMETHYLDIZINCOCENE AND -DIKETIMINATO COMPLEXES OF MAGNESIUM(I) AND (II) 33 1. Introduction 33 2. Pentamethylcyclopentadienyl zinc(I) dimer, {Zn( 5-C5Me5)}2 37 A. Pentamethylcyclopentadienyl potassium 38 B. Bis(pentamethylcyclopentadienyl)zinc(II) 38 C. Bis(pentamethylcyclopentadienyl)dizinc(I) 39 3. -diketiminato complexes of magnesium(I)/(II) 40 A. {2,4-bis-(2,6-diisopropylphenylimido)pentyl}(diethylether) iodomagnesium(II), {HC(CMeNC6H3-2,6-Pri 2)2}MgI(OEt2) 41 B. {2,4-bis-(mesitylimido)pentyl}(diethylether) iodidomagnesium(II),{HC(CMeNC6H2-2,4,6-Me3)2}MgI(OEt2) 42 C. Bis{2,4-bis-(2,6-diisopropylphenylimido)pentyl}dimagnesium(I) [{HC(CMeNC6H3-2,6-Pri 2)2}2Mg]2 43 D. Bis{2,4-bis-(mesitylimido)pentyl}dimagnesium(I), [{HC(CMeN(C6H2-2,4,6-Me3)}Mg]2 44 Chapter Four STERICALLY CROWDED - AND -BONDED METAL ARYL COMPLEXES 47 1. Introduction 47 2. Dimesityliron(II) dimer and dimesityldipyridineiron(II) (Mes = Mesityl = C6H2-2,4,6-Me3) 50 A. Tetramesityldiiron(II) dimer (FeMes2)2 (Mes = 2,4,6-trimethylphenyl) 51 B. Dimesityldi(pyridine)iron(II) FeMes2py2 (py = C5H5N) 54 3. Homoleptic, two-coordinate open-shell 2,6-dimesitylphenyl complexes of lithium, manganese, iron, and cobalt 56 A. 1-Iodo-2,6-bis(2,4,6-trimethylphenyl)benzene, 2,6-dimesitylphenyl iodide 57 B. Bis{ -2,6-bis(2,4,6-trimethylphenyl)phenyl}dilithium, 2,6-dimesitylphenyllithium dimer 58 C. Bis{2,6-bis(2,4,6-trimethylphenyl)phenyl}manganese(II), (bis(2,6-dimesitylphenyl)manganese(II)) 59 D. Bis{2,6-bis(2,4,6-trimethylphenyl)phenyl}iron(II), bis(2,6-dimesitylphenyl)iron(II) 59 E. Bis{2,6-bis(2,4,6-trimethylphenyl)phenyl}cobalt(II),bis(2,6-dimesitylphenyl)cobalt(II) 60 4. Monomeric group 14 diaryls bis{2,6-bis(2,4,6-trimethylphenyl)phenyl} germanium(II), tin(II), or lead(II), M{C6H3-2,6-Mes2)2 and bis{2,6-bis(2,6- diisopropylphenyl)phenyl}germanium(II), tin(II), or lead(II), M{C6H3-2,6-Dipp2}2 (M = Ge, Sn, or Pb
• Mes = C6H2-2,4,6-Me3
• Dipp = C6H3-2,6-Pri2) 61 5. m-terphenylgallium chloride complexes 65 A. {Bis(diethylether)lithium}{trichlorido(2,6-diphenyl)phenylgallate}, {Li(Et2O)2}{(C6H3-2,6-Ph2)GaCl3} 66 B. Chlorido{bis(2,6-dimesitylphenyl)}gallium, (2,6-Mes2C6H3)2GaCl 67 6. {(18-crown-6)bis(tetrahydrofuran)potassium}{bis(1,2,3,4- 4-anthracene)metallates} of cobalt(-I) and iron(-I),{K(18-crown-6)(THF)2} {M( 4-C14H10)2}, M= Co, Fe 67 A. {(18-crown-6)bis(tetrahydrofuran)potassium}{bis(1,2,3,4- 4-anthracene)cobaltate}, {K(18-crown-6)(THF)2}{Co(C14H10)2} 69 B. {(18-crown-6)bis(tetrahydrofuran)potassium}{bis(1,2,3,4- 4-anthracene)ferrate}, {K(18-crown-6)(THF)2}{Fe(C14H10)2} 70 7. {Bis(1,2-dimethoxyethane)potassium}{bis(1,2,3,4- 4-anthracene) cobaltate}, {K(DME)2}{Co( 4-C14H10)2} 72 8. Cyclopentadienyl and pentamethylcyclopentadienyl naphthalene ferrates 76 A. Bis(tetrahydrofuran)lithium cyclopentadienyl(1,2,3,4- 4-napthalene) ferrate, [{Li(thf)2}{CpFe( 4-C10H8)}] 78 B. (18-crown-6)potassium pentamethylcyclopentadienyl(1,2,3,4- 4- napthalene)ferrate, [K(18-crown-6){Cp Fe( 4-C10H8)}] 79 Chapter Five TERPHENYL LIGANDS AND COMPLEXES 85 1. Introduction 85 2. m-Terphenyl iodo and lithium reagents featuring 2,6-bis-(2,6- diisopropylphenyl) substitution patterns and an m-terphenyl lithium etherate featuring the 2,6-bis-(2,4,6-triisopropylphenyl) substitution pattern 89 A. 1-bromo-2,6-diisopropylbenzene, 1-Br-2,6-Pri2C6H3
• DippBr) 90 B. 1-iodo-2,6-bis(2,6-diisopropylphenyl)benzene (IC6H3-2,6-Dipp2) 92 C. Bis{2,6-bis(2,6-diisopropylphenyl)phenyl}dilithium,(LiC6H3-2,6-Dipp2)2 94 D. 2,6-bis(2,6-diisopropylphenyl)phenyllithiumetherate 95 E. 2,6-bis(2,4,6-triisopropylphenyl)phenyllithiumetherate{(Et2O)LiC6H3-2,6-Trip2} 96 3. 2,6-dimesitylaniline (H2NC6H3-2,6-Mes2) and 2,6-bis(2,4,6- triisopropylphenyl)aniline (H2NC6H3-2,6-Trip2) 98 A. 2,6-dimesitylphenylazide, 2,6-Mes2C6H3N 99 B. 2,6-dimesitylaniline, 2,6-Mes2C6H3NH2 100 C. 2,6-bis(2,4,6-triisopropylphenyl)iodobenzene, 2,6-Trip2C6H3I 101 D. 2,6-bis(2,4,6-triisopropylphenyl)azidobenzene,2,6-Trip2C6H3N3 102 E. 2,6-bis(2,4,6-triisopropylphenyl)aniline, 2,6-Trip2C6H3NH2 103 4. Bis-2,6-(2,6-diisopropylphenyl)aniline 105 A. 1-azido-bis-2,6-(2,6-diisopropylphenyl)benzene,2,6-Dipp2H3C6N3 106 B. Bis-2,6-(2,6-diisopropylphenyl)aniline, 2,6-Dipp2H3C6NH2 107 5. Bis-2,6-(2,4,6-trimethylphenyl)phenylformamide and isocyanide,Bis-2,6-(2,6-diisopropylphenyl)phenylformamide and isocyanide 109 A. 2,6-dimesitylphenyl formamide {2,6-Mes2H3C6N(H)C(O)H} 110 B. 2,6-dimesitylphenyl isocyanide (2,6-Mes2H3C6NC) 111 C. 2,6-bis-(diisopropylphenyl)phenyl formamide{2,6-Dipp2H3C6N(H)C(O)H} 112 D. 2,6-bis-(diisopropylphenyl)phenyl isocyanide (2,6-Dipp2H3C6NC) 113 6. Synthesis of the terphenylthiols: 2,6-bis(2,6-diisopropylphenyl)phenylthiol,2,6-bis(2,4,6-triisopropylphenyl)phenylthiol, and bis{2,6-bis(2,4,6-triisopropylphenyl)phenylthiolato}dilithium 116 A. 2,6-bis(2,6-diisopropylphenyl)phenylthiol 117 B. 2,6-bis(2,4,6-triisopropylphenyl)phenylthiol 118 C. Bis{2,6-bis(2,4,6-triisopropylphenyl)phenylthiolato}dilithium 119 7. Sterically encumbered terphenols: 2,6-bis(2,4,6-trimethylphenyl)phenol and 2,6-bis(2,6-diisopropylphenyl)phenol 120 A. 2,6-bis(2,6-diisopropylphenyl)phenol 121 B. Bis(2,4,6-trimethylphenyl)phenol 121 Chapter Six SYNTHETIC ROUTES TO WHITE PHOSPHORUS (P4) AND ARSENIC TRIPHOSPHIDE (AsP3) 123 1. Introduction 123 2. Facile preparation of white phosphorus from red phosphorus:Preparation A 125 3. Synthesis of white phosphorus (P4) from red phosphorus:Preparation B 127 4. Arsenic triphosphide, AsP3 130 A. Tris(2,6-diisopropylphenoxy)niobiumdichloride {Cl2Nb(ODipp)3} and Tris(2,6-diisopropylphenoxy)niobiumdichloride(tetrahydrofuran) {Cl2Nb(ODipp)3(THF)} 131 B. {Na(THF)3}{P3Nb(ODipp)3} 132 C. Arsenic Triphosphide AsP3 133 Chapter Seven SYNTHETIC ROUTES TO PHOSPHIDO AND ARSENIDO DERIVATIVES OF THE GROUP 13 METALS ALUMINUM, GALLIUM, AND INDIUM, TRIS(TERT-BUTYL)GALLIUM AND ITS REACTIONS WITH AMMONIA, AND THE ALUMINUM(I) SPECIES PENTAMETHYLCYCLOPENTADIENYL ALUMINUM TETRAMER 135 1. Introduction 135 2. Dinuclear phosphido and arsenido derivatives of aluminum, gallium, and indium {Me2M( -EBut2)}2, M= Al, Ga, In
• E = P, As 137 A. Preparation of {Me2M( -EBut2)}2 Complexes: M= Al,Ga, In
• E = P, As 138 3. Tris(tert-butyl)gallane, its ammonia complex, and the amidobis(tert-butyl)gallane trimer tris( -amido)hexa(tert-butyl)trigallium 140 A. Tri-tert-butylgallane 141 B. Ammonia complex of tri-tert-butylgallane 142 C. Tris( -amido)hexa-tert-butyltrigallium: The trimer {But2Ga ( -NH2)}3 143 4. Reductive elimination as a convenient pathway to tetrameric ( 5-pentamethylcyclopentadienyl)aluminum(I) {(AlCp )4} (Cp = 5-C5Me5) 144 A. Potassium pentamethylcyclopentadienide KCp 146 B. Bis(pentamethylcyclopentadienyl)aluminumhydride (Cp 2AlH) 146 C. Tetrameric ( 5-pentamethylcyclopentadienyl)aluminum(I){(AlCp )4} 147 5. A facile synthesis of tetrameric (n5-pentamethylycycloclopentadienyl) aluminum(I) {Al(n5-C5Me5)}4 147 A. (n5-pentamethylcyclopentadienyl)aluminumdichloride 149 B. Tetrameric (n5-pentamethylcyclopentadienyl)aluminum(I) (AlCp )4 149 6. Tris(pentafluorophenyl)aluminum(toluene): Al(C6F5)3(C7H8) 150 A. Tris(pentafluorophenyl)aluminum(toluene) 151 Chapter Eight SYNTHESIS OF SELECTED TRANSITION METAL AND MAIN GROUP COMPOUNDS WITH SYNTHETIC APPLICATIONS 155 1. Introduction 155 2. Synthesis of gold(I) and gold(II) amidinate complexes 157 A. Synthesis of gold(I) amidinate complexes 158 B. Synthesis of gold(II) amidinate complexes 161 3. A nickel-iron thiolate and its hydride 166 A. (1,2-bis(diphenylphosphino)ethane)(1,3-propanedithiolato) nickel(II) 167 B. (1,2-bis(diphenylphosphino)ethane)nickel(I)( -1,3- propanedithiolato)tricarbonyliron(I) 168 C. (1,2-bis(diphenylphosphino)ethane)nickel(II)( -hydrido)( -1,3-propanedithiolato)tricarbonyliron(II) tetrafluoroborate 169 4. Dimethyl sulfoxide and organophosphine complexes of ruthenium(II) halides 171 A. cis-tetrakis(dimethylsulfoxide)ruthenium(II)dichloride 172 B. cis-bis{1,2-bis(diphenylphosphino)ethane}ruthenium(II) dichloride 174 C. Bis{1,2-bis(diphenylphosphino)ethane}chlororuthenium(II) hexafluorophosphate 174 D. trans-bis{1,2-bis(diphenylphosphino)ethane}ruthenium(II) dichloride 176 5. Synthesis of {CrIII(NCMe)6}(BF4)3 and {CrIII(NCMe)5F} (BF4)2*MeCN 177 A. Hexakis(acetonitrile)chromium(III) tetrafluoroborate, {CrIII(NCMe)6}(BF4)3 177 B. Pentakis(acetonitrile)fluorido chromium(III) tetrafluoroborate, {CrIIIF(NCMe)5}(BF4)2 178 6. (1R,2R-diaminocyclohexane)oxalatoplatinum(II), oxaliplatin 179 7. Tris(dibenzylideneacetone)dipalladium(0) 183 A. Synthesis of Pd2dba3 CHCl3 185 B. Purity determination and repurification of Pd2dba3 186 C. Stability 187 8. Tetraalkylammonium salts of tetra(fluoroaryl)borate anions 188 A. Tetraalkylammonium salts of [B(C6F5)4] 189 B. Tetraalkylammonium salts of [B{C6H3-3,5-(CF3)2}4] 191 9. Titanium tris(N-tert-butyl, 3,5-dimethylanilide) 193 10. Tetrachlorido(tetramethylethylenediamine)tantalum(IV),TaCl4(TMEDA) 196 A. Tetrachlorido(tetramethylethyenediamine)tantalum(IV),TaCl4(TMEDA) 197 11. Synthesis of 1,3,5-tri-tert-butylcyclopenta-1,3-diene and its metal complexes Na{1,2,4-(Me3C)3C5H2} and Mg{ 5-1,2,4-(Me3C)3C5H2}2 199 A. Method A (Phase Transfer) 199 B. Method B (Grignard Procedure) 201 C. Sodium(1,2,4-tri-tert-butyl)cyclopentadienide 203 D. Magnesium(II)bis(1,2,4-tri-tert-butyl)cyclopentadienide 203 Cumulative Contributor Index 205 Cumulative Subject Index 215 Cumulative Formula Index 245

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詳細情報

• NII書誌ID(NCID): BA01731242
• ISBN:
  • 0070485178
  • 0070132089
  • 0070713200
  • 0070485216
  • 007004015X
  • 0070443270
  • 0471033936
  • 047104542X
  • 0471077151
  • 0471865206
  • 0471888877
  • 0471818739
  • 0471834416
  • 0471618748
  • 0471504858
  • 0471509760
  • 0471544701
  • 0471305073
  • 0471152889
  • 0471249211
  • 0471208256
  • 9780471647508
  • 9780471682554
  • 9781118744871
  • 9781119477730
• LCCN: 39023015
• 出版国コード: us
• タイトル言語コード: eng
• 本文言語コード: eng
• 出版地: New York
• ページ数/冊数: v.
• 大きさ: 24 cm
• 分類:
  • NDC8 : 434
  • NDC7 : 434.8
• 件名:
  • LCSH : Inorganic compounds -- Synthesis