Lanthanide shift reagents in stereochemical analysis
著者
書誌事項
Lanthanide shift reagents in stereochemical analysis
（Methods in stereochemical analysis, v. 5）
VCH, c1986
- us
- gw
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注記
Includes bibliographies and indexes
内容説明・目次
内容説明
This collection of five articles by leading authorities provides the first comprehensive review of LSR compounds in the context of stereochemical analysis. It illustrates their application in determining the configuration of organic compounds. The authors discuss computer-aided approaches to elucidating the geometry of LSR-substrate complexes, show solutions of complex stereochemical problems, and present the new and successful reagent class of Ag(I)Ln(III) diketonate complexes. Other subjects of current interest are stereochemical analyses of diastereotopic groups, ring conformations, bridged polycyclic compounds, and deuterium labeling.
目次
- An Introduction to Lanthanide Shift Reagents
- Computer Approaches to the Geometry of the LSR-Substrate Complex: Geometry of Shift Reagents-Substrate Complexes, Simulation of Induced Chemical Shifts
- The Nature of the LSR-Substrate Complex
- Solutions to Stereochemical Problems
- Binuclear Lanthanide(III)-Silver(I) NMR Shift Reagents
- Author Index
- Subject Index.
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