Semiconductor electrodes
著者
書誌事項
Semiconductor electrodes
（Studies in physical and theoretical chemistry, 55）
Elsevier, 1988
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注記
Includes bibliography and index
内容説明・目次
内容説明
Semiconductors have been studied as electrodes in electrochemical systems since the mid-1950's. However, it was not until the 1970's that the search for alternative energy sources, especially solar energy, led to an enormous expansion in semiconductor electrode research. One attractive option for solar energy conversion is the semiconductor liquid-junction solar cell, which can be designed to produce either electrical power or fuel such as hydrogen. Consequently the number of papers published concerning semiconductor electrodes has rapidly increased. Previous books have principally focused on the underlying theory (largely from solid state physics) and principles of operation of all semiconductor electrodes. It therefore seemed both useful and appropriate to review the field with the intention of collating information for each semiconductor or family of semiconductors, with contributions from authors who are all recognized experts in their field. Each chapter is devoted to critically assessing the recent literature on a particular semiconductor or family of semiconductors.
目次
1. Semiconductor Electrode Concepts and Terminology (H.O. Finklea). Introduction. Fundamentals: The energy band model. A model for electron transfer reactions. Measurement of the flatband potential. Perturbations of the ideal model. Miscellaneous topics. 2. Titanium Dioxide (TiO 2 ) and Strontium Titanate (SrTiO 3 ) (H.O. Finklea). Bulk properties. Electrode preparation and surface properties. The flatband potential. Electrochemistry and photoelectrochemistry. Polycrystalline electrodes. Photoelectrochemical reactions of powders. Miscellaneous topics. 3. Iron Oxide (Fe 2 O 3 ) (M. Anderman, J.H. Kennedy). Bulk properties. Electrode preparation. Electrochemistry and photoelectrochemistry. Solar energy conversion devices. 4. Tin Oxide (SnO 2 ), Indium Oxide (In 2 O 3 ), and Tungsten Oxide (WO 3 ) (A. Nanthakumar, N.R. Armstrong). Tin Oxide - SnO 2 . Indium Oxide - In 2 O 3 . Tungsten Oxide - WO 3 . 5. Silicon (Si) and Germanium (Ge) (N.S. Lewis, A.B. Bocarsly). Semiconductor bulk properties. Electrode preparation and surface properties of silicon. Electrochemistry and photoelectrochemistry of single crystals. Miscellaneous topics on silicon. Germanium photoelectrochemistry. 6. Cadmium Chalcogenides (CdS, CdSe, CdTe) (R.D. Rauh). Bulk properties and preparation. Electrochemistry and photoelectrochemistry of Cd chalcogenide single crystals. Polycrystalline and thin film photoelectrodes. Future directions. 7. Gallium Phosphide (GaP) (D.S. Ginley, M.A. Butler). Materials and Electronic Properties. GaP Photoelectrochemistry. Chemistry of the GaP-Electrolyte Interface. 8. Gallium Arsenide (GaAs) (K.W. Frese, Jr.). Reference data. Sample preparation. Adlayers on GaAs surfaces and fermi level pinning. Electrochemical reactions. Photoelectrochemistry of GaAs. 9. Indium Phosphide (InP) (L.F. Schneemeyer et al.). Bulk properties. Electrode preparation and surface properties. Electrochemistry and photoelectrochemistry of single crystals. Polycrystalline InP electrodes. Hot carrier injection. Summary and future directions. 10. Molybdenum and Tungsten Dichalcogenides (B. Scrosati). Molybdenum and tungsten dichalcogenides. Bulk properties. Preparation of electrodes and photoelectrochemical cells. Photoelectrochemical characteristics of molybdenum and tungsten dichalcogenide electrodes. Influence of the surface morphology on the photoelectrochemical behaviour of layered semiconductors. Photoelectrochemical applications of molybdenum and tungsten dichalcogenides. Photointercalation. Photoelectrochemical behaviour of molybdenum and tungsten dichalcogenide electrodes in non-aqueous electrolytes. Polycrystalline molybdenum and tungsten dichalcogenide electrodes. Index.
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