Crystallization processes under hydrothermal conditions
Author(s)
Bibliographic Information
Crystallization processes under hydrothermal conditions
(Studies in Soviet science)
Consultants Bureau, [1973]
- Uniform Title
-
Issledovanie prot︠s︡essov kristallizat︠s︡ii v gidrotermalʹnykh uslovii︠a︡kh. English
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Note
Translation of Issledovanie prot︠s︡essov kristallizat︠s︡ii v gidrotermalʹnykh uslovii︠a︡kh
Includes bibliographical references
Description and Table of Contents
Description
This collection conta ins the results of a number of investiga- tions which have been carried out in the Hydrothermal Synthesis Laboratory of the Institute of Crystallography, Academy of Sciences of the USSR; it constitutes a continuation of an earlier collection which appeared in 1968: Hydrothermal Synthesis of Crystals. Problems associated with the synthesis of oxides, simple and complex sulfides, carbonates, silicates, and germanates are consid- ered, and a great deal of factual material relating to the growth of single crystals of some of these compounds on a seed is presented. Some of the articles pay special attention to the kinetic asp- ect of the growth of crystals; the conditions of growth are relat- ed to the morphological characteristics of the growing faces, and the relationship between the habit of the crystals and the oomposi- tion and constitution of the solutions is considered. A fair number of articles are concerned with the crystalliza- tion of new compounds, most of which have now been synthesized under hydrothermal conditions for the very first time; these in- clude ternary chalcohalides of composition AVBvIVVII. zirconates, lithium silicates, and germanates.
The collection also contains a description of the apparatus used for precision measurements at high temperatures and pres- sures. We hope that this publication will present a better idea of the special characteristics of the hydrothermal method of synthes- izing and .growing crystals, and will prove useful to all those in- terested in this field of knowledge.
Table of Contents
Some Problems of Hydrothermal Crystallization.- Synthesis of Zincite by the Hydrothermal Method.- Crystallization of the Oxides of Titanium Subgroup Metals.- Synthesis of Single Crystals of Ternary Chalcohalides.- Crystallization of Antimonite (Sb2S3).- Crystallization in the Systems PbO-TiO2-KF-H2O and PbO-ZrO2-KF-H2O.- Growth Characteristics of Calcite Crystals in Aqueous Solutions of Carbonic Acid.- Dissociation Curves of Trigonal Carbonates.- Solubility of Sodalite in Aqueous Solutions of NaOH under Hydrothermal Conditions.- Crystallization of Sodalite on a Seed.- Hydrothermal Crystallization of Lithium Silicates. Synthesis of Spodumene.- Hydrothermal Synthesis of Germanates.- Crystallization Kinetics of Sodium Zincogermanate Na2ZnGeO4.- Controlling the Growth of Crystals in Autoclaves.- Apparatus for Precision Research in Hydrothermal Experiments.
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