Thermodynamics of rock-forming crystalline solutions
Author(s)
Bibliographic Information
Thermodynamics of rock-forming crystalline solutions
(Minerals, rocks and inorganic materials, 8)
Springer-Verlag, 1973
- : U.S.
- : Germany
Available at 43 libraries
  Aomori
  Iwate
  Miyagi
  Akita
  Yamagata
  Fukushima
  Ibaraki
  Tochigi
  Gunma
  Saitama
  Chiba
  Tokyo
  Kanagawa
  Niigata
  Toyama
  Ishikawa
  Fukui
  Yamanashi
  Nagano
  Gifu
  Shizuoka
  Aichi
  Mie
  Shiga
  Kyoto
  Osaka
  Hyogo
  Nara
  Wakayama
  Tottori
  Shimane
  Okayama
  Hiroshima
  Yamaguchi
  Tokushima
  Kagawa
  Ehime
  Kochi
  Fukuoka
  Saga
  Nagasaki
  Kumamoto
  Oita
  Miyazaki
  Kagoshima
  Okinawa
  Korea
  China
  Thailand
  United Kingdom
  Germany
  Switzerland
  France
  Belgium
  Netherlands
  Sweden
  Norway
  United States of America
-
Science and Technology Library, Kyushu University
: U.S.027232003082545,
: Germany068222480059875
Note
Bibliography: p. [179]-186
Description and Table of Contents
Table of Contents
and Acknowledgements.- I. Thermodynamic Relations in Crystalline Solutions.- 1. Crystalline Solutions.- 2. Choice of a Chemical Component.- 3. General Properties of Solutions.- a) Chemical Potential.- b) Ideal Crystalline Solution.- c) Non-Ideal Solutions and Excess Functions of Mixing.- d) Chemical Potential and Activity of a Component in a Mineral.- II. Thermodynamic Models for Crystalline Solutions.- 1. Regular Solution Model.- a) Zeroth Approximation.- b) Simple Mixture Model.- c) Quasi-Chemical Model.- 2. General Relations for Binary, Ternary, and Quaternary Nonideal Crystalline Solutions.- III. Thermodynamic Stability of a Solution.- 1. Critical Mixing.- 2. General Conditions.- a) Simple Mixture.- b) General Nonideal Solution.- 3. Spinodal Decomposition.- 4. Critical Mixing in Quasi-Chemical Approximation.- 5. Immiscibility in Ternary Crystalline Solutions.- 6. Formation of Miscibility Gaps in a Ternary Simple Mixture.- 7. Formation of Miscibility Gap in Asymmetric Ternary Solutions.- 8. Immiscibility in Mineral Systems.- a) Interpretation of Sequences of Mineral Assemblages.- b) Intrinsic and Extrinsic Stability.- c) Immiscibility in Garnets.- IV. Composition of Coexisting Phases.- 1. Ideal Solution Model.- a) Distribution of a Component between Two Ideal Binary Crystalline Solutions.- b) Coexisting Ternary Ideal Solutions.- 2. Nonideal Solutions.- a) Distribution of a Component between Two Simple Mixtures.- b) Coexisting Regular Ternary Solutions.- 3. Distribution of a Cation between Two or More Multicomponent Minerals.- 4. Composition of Coexisting Minerals and Chemical Equilibrium in Igneous Rocks.- 5. Physico-Chemical Conditions of Formation of Mineral Assemblages as Inferred from Composition of Coexisting Phases.- 6. Stability of Orthopyroxene.- 7. Distribution of Trace Elements.- V. Measurement of Component Activity Using Composition of Coexisting Minerals.- 1. Compositional Data Available on a Complete Distribution Isotherm.- 2. Composition Data on a Complete Distribution Isotherm and the Activity-Composition Relation in One of the Two Coexisting Phases.- 3. Examples of Calculations.- VI. Measurement of Component Activities by Analysis of Two-Phase Data.- 1. Symmetrical Mixtures.- a) Simple Mixture.- b) Symmetrical Mixture of Higher Order.- 2. Asymmetrical Solutions.- a) Subregular Model.- b) Quasi-Chemical Approximation.- 3. Example of Calculation of Functions of Mixing: The CaWO4-SrWO4 System.- 4. Coexisting Phases with Different Crystal Structures.- VII. Order-Disorder in Silicates.- 1. Order-Disorder and the Crystalline Solution Models.- 2. Intracrystalline Ion Exchange and Site Activities.- 3. Thermodynamic Functions of Mixing.- 4. Kinetics of Order-Disorder.- VIII. Pyroxene Crystalline Solution.- 1. Orthopyroxene.- a) Intersite Ion Exchange.- b) Order-Disorder on Individual Sites and the Choice of a Solution Model.- c) Determination of Site Occupancy in Heated Orthopyroxenes.- d) Sites as Simple Mixtures.- e) Thermodynamic Functions of Mixing with Sites as Simple Mixtures.- f) Sites as Solutions with Quasi-chemical Approximation.- g) Activity-Composition Relation at 873 K.- h) Unmixing.- 2. Calcic Pyroxenes.- a) Intracrystalline Distribution of Fe2+ Mg and Ca.- b) Thermodynamic Nature of Mixing in M 2 from Data on Orthoenstatite-Diopside Binodal.- IX. Olivine Crystalline Solution.- 1. Bowen and Schairer's Data.- 2. Fe-Mg Olivines at 1200 C.- 3. The System Monticellite (CaMgSiO 4)-Forsterite (Mg2SiO4).- X. Feldspar Crystalline Solution.- 1. Order-Disorder.- a) Potassium Feldspars.- b) Sodium Feldspar.- c) Calcium Feldspar.- d) Process of Ordering.- 2. Long-Range Ordering Parameters and the Calculation of Al Site-occupancy from Crystal-structural Data.- 3. Ideal Configurational Entropy.- 4. Thermodynamic Functions of Mixing in Binary Feldspars.- a) Monoclinic Alkali Feldspar.- b) Plagioclase.- c) Ternary Feldspars.- XI. Crystalline Solutions and Geothermometry.- 1. Intercrystalline Equilibria.- a) Distribution of a Component between Coexisting Simple Mixtures.- b) Coexisting Plagioclase and Alkali Feldspar.- c) Distribution of Fe and Mg in Coexisting Minerals.- d) Distribution of Other Elements.- 2. Order-Disorder.- a) Fe-Mg Silicates.- b) Fe-Mg Order-Disorder in Orthopyroxene.- c) Order-Disorder in Feldspars.- 3. Other Geothermometers.- Appendix: Computer Programs for Calculation of Thermodynamic Functions of Mixing in Crystalline Solutions.- References.
by "Nielsen BookData"