Organic syntheses with noble metal catalysts
著者
書誌事項
Organic syntheses with noble metal catalysts
（Organic chemistry : a series of monographs, v. 28）
Academic Press, 1973
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注記
Includes bibliographies and indexes
内容説明・目次
内容説明
Organic Chemistry, Volume 28: Organic Syntheses with Noble Metal Catalysts provides information pertinent to the catalysis by noble metals, which is presented in a form as to be of use to those interested in organic synthesis. This book discusses the mechanistic aspects of reactions. Organized into nine chapters, this volume begins with an overview of catalytic dehydrogenation over platinum metals, which provides a convenient method for synthesis of organic compounds. This text then examines the mechanisms and kinetics of homogeneous hydrogenation. Other chapters consider the oxidation of organic compounds in the presence of noble metal catalysts that may affect a variety of changes, including introduction of alcohol, epoxide, carbonyl, and halogen functions into the molecule. This book discusses as well the differences between osmium tetroxide and ruthenium tetroxide in their reactions with organic compounds. The final chapter deals with noble metal catalysts. This book is a valuable resource for synthetic organic chemists.
目次
PrefaceChapter 1. Dehydrogenation Catalysts Experimental Procedures Aromatization Formation of New Bonds Dehydrogenation of Ketones to Phenols Dealkylation and Isomerization Hydrogen Exchange Processes Loss of Functional Groups ReferencesChapter 2. Homogeneous Hydrogenation Catalysts Olefins Sulfur Compounds Labeling Diminished Disproportionation Asymmetric Hydrogenations Miscellaneous ReferencesChapter 3. Oxidation Oxidation of Olefins in Aqueous Systems Oxidation of Olefins in Nonaqueous Systems Oxidation of Complex Olefins Oxidative Coupling Acetoxylation Oxidation of Alkylaromatics Oxidation of Alcohols Oxidative Dehydrogenation N-Dealkylation ReferencesChapter 4. Osmium and Ruthenium Tetroxides as Oxidation Catalysts Osmium Tetroxide Metal Chlorates as Oxidants Peroxides as Oxidants Air as Oxidant Periodate as Oxidant Hypochlorite as Oxidant Hexacyanoferrate as Oxidant Disproportionation Ruthenium Tetroxide Oxidation of Aromatics Oxidation of Alcohols Oxidation of Olefins Oxidation of Acetylenes Ruthenium Tetroxide-Sodium Hypochlorite ReferencesChapter 5. Isomerization Double-Bond Migration Configurational Changes Skeletal Isomerization Aromatizations Valence Isomerization ReferencesChapter 6. Oligomerizations, Telomerizations, and Condensations Oligomerization of Olefins Oligomerization of Substituted Olefins Telomerization of Olefins Oligomerization of Dienes Addition of Dienes to Olefins Oligomerization of Acetylenes Telomerization of Dienes Condensations ReferencesChapter 7. Carbonylation and Hydroformylation Catalysts Acetylenes Amines Azides Alcohols Halogen Compounds Olefins Carbonylation of Dienes Carbonylation of Olefinic Compounds Nitro Compounds ReferencesChapter 8. Decarbonylation and Desulfonylation Decarbonylation Aliphatic Aldehydes Unsaturated Aldehydes Aromatic Aldehydes Acid Halides Aroyl Cyanides Ketones Anhydrides Alcohols Ethers Esters and Acids ss-Ketoamides Formate Esters Desulfonylation ReferencesChapter 9. Silicon Chemistry Catalysts for Hydrosilylation of Olefins Addition of Silanes to Olefins Addition of Silanes to Diolefins Addition of Silanes to Substituted Olefins Hydrosilylation of Acetylenes Addition to the Nitroso Function Addition of Aminosilicon Hydrides to Olefins Dehydrogenation Acid Halides Carbon-Silicon Bond Cleavage ReferencesAuthor IndexSubject Index
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