Electron transfer reactions of complex ions in solution
著者
書誌事項
Electron transfer reactions of complex ions in solution
（Current chemical concepts, A series of monographs）
Academic Press, 1970
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注記
Includes bibliographies
内容説明・目次
内容説明
Electron Transfer Reactions of Complex Ions in Solution covers the significant development of some important area of electron transfer reactions of complex ions. This four-chapter book emerged from a series of lectures at the Polytechnic Institute of Brooklyn in November and December 1967. Chapter I presents research studies in cation hydration. This chapter describes principal methods for composition determination of the first coordination spheres of the aquo ions. Chapter II examines the distinction between reactions in which electron transfer takes place from one primary bond system to another. Chapter III discusses some aspects of ligand effects in electron-transfer reactions. This chapter demonstrates that differences in the behavior of systems can be expected at least in the extremes of mechanisms. Chapter IV deals with the history, principles and applications of the induced electron-transfer effect. This book is of great value to electrochemists, students, and researchers.
目次
ForewordChapter I. Introduction Of The Reagents: Studies In Hydration Of Cations I. Introduction II. Summary of Results III. Application of the Methods IV. Relations Between Substitution Rates V. Comments on Rates Summarized in Table 1-1 VI. Problems ReferencesChapter II. Description Of The Activated Complexes For Electron Transfer I. Introduction II. The Outer-Sphere Activated Complex III. The Inner-Sphere Activated Complex ReferencesChapter III. Some Aspects Of Ligand Effects In Electron Transfer Reactions I. Introduction II. Simple Ligands III. Activation Parameters IV. The Mechanism of Electron Transfer V. Conclusion ReferencesChapter IV. Induced Electron Transfer I. Introduction II. History III. Evidence for the Formation of an Intermediate IV. The Oxidation of Pentaamminepyridinemethanolcobalt (III) by Ce(IV) V. Low-Spin Co(II) as an Intermediate VI. Other Systems ReferencesSubject Index
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