Structure and chemistry

著者

• Rahman, Atta-ur-

書誌事項

Structure and chemistry

edited by Atta-ur-Rahman

（Studies in natural products chemistry / edited by Atta-ur-Rahman, v. 7, 9, 15, 17, 19, 20）

Elsevier, 1990-

• pt. A
• pt. B
• pt. C
• pt. D
• pt. E
• pt. F

注記

Includes bibliographies and index

内容説明・目次

巻冊次

pt. F ISBN 9780444501059

内容説明

Natural Products Chemistry continues to grow at an increasing pace and this growth is reflected in the present volume of Studies in Natural Products Chemistry, which is the 20th of this series. The first 20 volumes were largely devoted to structure and synthesis of various classes of natural products, irrespective of their bioactivity. Subsequent volumes of this series will however be devoted to the chemistry of bioactive natural products and will therefore a departure from the earlier volumes.The present volume contains contributions from a number of eminent scientists and covers interesting reviews on terpenes, alkaloids and other types of natural products reported from terrestrial and marine sources. Comprehensive indexes covering all the 20 volumes have been prepared which include a Cumulative General Subject Index along with more focused Cumulative Indices on Organic Synthesis, Pharmacological Activity and Biological Source. This comprehensive indexing of the volumes should make the entire series much more valuable and user-friendly.

巻冊次

pt. C ISBN 9780444820839

内容説明

Natural product chemistry covers a fascinating area of organic chemistry and its study has enriched organic chemistry in a myriad of different ways. In recent years the thrust has been in three major directions: advances in stereoselective synthesis of bioactive natural products, developments in structure elucidation of complex natural products through the applications of multidimensional NMR and mass spectroscopy, and the integration of bioassay procedures with the isolation processes leading to the isolation of active principles from the extracts. The present volume reflects these developments, and the growing emphasis on bioactive natural products, chemical constituents of echinoderms, diterpenoids from Rabdosia and Eremophila sp., structural studies on saponins, marine sesquiterpene quinones and antimicrobial activity of amphibian venoms. The reviews on bioactive metabolites of Phomophis, cardenolide detection by ELISA, xenocoumacins and bioactive dihydroisocoumarins, CD studies of carbohydrate-molybdate complexes, oncogene function inhibitors from microbial secondary metabolites and Gelsemium and Lupin alkaloids present frontier developments in several areas of natural product chemistry. It is hoped that the present volume, which contains articles by eminent authorities in each field, will be received with the same enthusiasm as the previous volumes of this series.

目次

Structure-activity relationships of highly sweet natural products (A.D. Kinghorn et al.). Structural studies on chemical constituents of Echinoderms (L. Minale et al). Recent advances in the chemistry of diterpenoids from Rabdosia species (Y. Takeda, H. Otsuka). Structural elucidation of saponins (G. Massiot, C. Lavaud). The chemistry of unusual terpenoids from the genus Eremophila (E.L. Ghisalberti). Marine sesquiterpene/quinones (R.J. Capon). Antimicrobial activity of amphibian venoms (G.G. Habermehl). Bioactive metabolites of the genus Phomopsis (Y.S. Tsantrizos). Detection of cardenolides by ELISA in plant sciences (K. Yoshimatsu et al.). The Xenocoumarins and related biologically active dihydroisocoumarins (B.V McInerney, W.C. Taylor). Circular dichroism of carbohydrate-molybdate complexes (Z. Shah et al.). Screening of oncogene function inhibitors from microbial secondary metabolites (K. Umezawa). Recent advances in the chemistry of Gelsemium alkaloids (H. Takayama, S. Sakai). Chemistry, biochemistry and chemotaxonomy of Lupine alkaloids in the Leguminosae (K. Saito, I. Murakoshi).

巻冊次

pt. D ISBN 9780444822659

内容説明

Rapid advances in chromatographic procedures, spectroscopic techniques and pharmacological assay methods have resulted in the discovery of an increasing number of new and interesting natural products from terrestrial and marine sources. The present volume contains comprehensive reviews on some of the major advances in this field which have taken place in recent years. The reviews include those on: novel metabolites from marine gastropods; the chemistry of marine natural products of the Halenaquinol family; secondary metabolites from Echinoderms and Bryozoans; triterpenoids and aromatic compounds from medicinal plants; chemistry and activity of sesquiterpenes from the genus Lactarius; the chemistry of bile alcohols; antifungal sesquiterpene dialdehydes; annonaceous acetogenins; nargenicin macrolides; and lignans and diarylheptanoids. Tropane alkaloids and phenolides formed by root cultures are also reviewed. Articles on natural Diels-Alder type adducts, the use of computer aided overlay for modelling the substrate binding domain of HLADH, applications of 170 NMR spectroscopy to natural product chemistry and the role of biological raw materials in synthesis are included. Volume 17 provides material of interest to natural products chemists.

目次

• Novel secondary metabolites of marine gastropods, M. Alam and K.L. Euler
• total synthesis and absolute stereochemistry of novel biologically active marine natural products of halenaquinol family - theoretical studies of CD spectra, N. Harada and T. Sugioka
• bryozoan secondary metabolites and their chemical ecology, A.J. Blackman and J.T. Walls
• structure and biological activity of triterpenoids and aromatic compounds from medicinal plants, R. Aquino et al
• sesquiterpenes and other secondary metabolites of genus lactarius (basidiomycetes) -chemistry and biological activity, G. Vidari and P. Vita-Finzi
• structure and biosynthesis of bile alcohols - disorders of cholesterol side-chain oxidation in cerebrotendinous xanthomatosis, B. Dayal et al
• antifungal sesquiterpene dialdehyde from the warburgia plants and their synergists, I. Kubo
• determination of relative and absolute configuration in the annonaceous acetogenins, E.A. Ramirez and T.R. Hoye
• the chemistry of the nargenicin macrolides, J. Kallmerten
• some aspects of the chemistry of lignans, R. Stevenson
• the chemistry of natural diarylheptanoids, G.M. Keseru and M. Nogradi
• tropane alkaloids in root cultures of solanaceous plants, M. Sauerwein et al
• phenolics in root cultures of medicinal plants, K. Ishimaru and K. Shimomura
• chemistry and biosynthesis of natural diels-alder type adducts from moraceous plants, T. Nomura et al
• modelling the substrate binding domain of horse liver alcohol dehydrogenase, HLADH, by computer aided substrate overlay, M. Aksela and A.C. Oehlschlager
• applications of 17O NMR spectroscopy to natural products chemistry, D.W. Boykin
• the role of biological raw materials in synthesis, J.H.P. Tyman.

巻冊次

pt. E ISBN 9780444828156

内容説明

This volume presents research work carried out over a wide front of natural product chemistry. It includes the synthesis of dendrobatid alkaloids, aspidosperma and related alkaloids and some natural products via aliphatic nitro derivatives, cannabinoids, brassinosteroids, quinocarcin and its relate compounds, mannostatins and cyclophellitols and derivatives of grandiflorenic acid and some related diterpines. The text also presents marine cyclic halo ether compounds, oxidative ring transformation furylcarbinols and stereoselective synthesis of C-branded nucleoside analogues. Work on novel polysaccharides from microorganisms and plants, the dereplication of plant-derived natural products, siderophores from fluorescent pseudomonas is also presented.

目次

• Recent advances in the synthesis of dendrobatid alkaloids
• synthesis of some aspidosperma and related alkaloids
• synthesis of natural products via aliphatic nitroderivatives
• steroespecific cann synthesis - the application of new techniques to a classical problem
• methods for construction of si of brassinosteroids
• totla synthesis of quinocarcin and its related compounds
• synthesis of mannosta and cyclophellitols, new cyclitol inhibitors for glycoside metabolism of glyvoproteins and glycolipi molecular rearrangements in the derivatives of grnadiflorenic acid [(-)-kaura-9(11), 16-diene-19-oic and some related diterpenes
• total syntheses of cyclic halo ether componds from marine origin
• oxida ring transformation of 2-furylcarbinols in natural product syntheses
• stereoselective synthesis of C branded nucleoside analogues
• bioactive marine macrolides
• hormones in the red swamp crayfish
• the structure and antigenicity of novel polysaccharides from microorganisms and plants
• the dereplicatio plant-derived natural products
• siderophones from fluorescent pseudomonas.

巻冊次

pt. A ISBN 9780444888297

内容説明

The increasing interest in natural product chemistry is due to the wealth of novel structures being discovered from both terrestrial and marine plant materials, and their potential for application in medicine. The present volume is the seventh of this series, and the third dealing with structural aspects of natural products. The chirality of natural products in relation to their biological activity, enzyme-carbohydrate interactions, and plant tissue culture as applied to the biosynthesis of terpenoids are dealt with in this work. Other chapters are concerned with oleanane triterpenes, bioactive constituents of mangrove plants and natural products from Artemisia. Contributions on toxins from echinoderms, biosynthesis of carotenoids, bioactive compounds from Simaroubaceous plants and plants used in African traditional medicine are also included. The last chapter is devoted to the chemistry of iridoids.

目次

Chirality as manifested in the biological activity of natural products (W. Gaffield). The use of synthetic substrate analogues in the study of enzyme-carbohydrate interactions (K. Bock, B.W. Sigurskjold). Synthesis of lower terpenoids and related compounds by plant tissue cultures (D.V. Banthorpe). Recent advances in oleanane triterpenes (G.B.R. Mallavarapu). Chemical constituents and bioactive compounds from mangrove plants (U. Kokpol et al.) Natural products from the genus Artemisia L. (J.A. Marco, O. Barbera). Toxins of echinoderms (G.G. Habermehl, H.C. Krebs). The stereochemistry of carotenoid biosynthesis (G. Britton). Biologically active compounds from Simaroubaceous plants (M. Okano et al.). Bioactive constituents of plants used in African traditional medicine (K. Hostettman, A. Marston). The chemistry of iridoids (A. Bianco). Subject index.

巻冊次

pt. B ISBN 9780444891655

内容説明

This ninth volume in the series, comprises twenty-five chapters written by outstanding experts at the forefront of their respective fields. Various aspects of the structure elucidation, synthesis, biosynthesis and biological properties of natural products from diverse marine, fungal, bacterial, amphibian and insect sources, as well as lower and higher plants are described. Physical techniques such as NMR and mass spectral methods are emphasized, and advances in enzyme-substrate interactions are also featured. The scope of information given in this book amply testifies to the enormous potential for the future development of natural products from the marine and terrestrial environments to provide the key biological agents for the future benefit of mankind from renewable resources.

目次

Preface (G.A. Cordell). X-Ray crystallographic studies on novel natural products from marine animals (M.I. Choudhary and J.C. Clardy). Marine norterpene cyclic peroxides: a stereochemical paper chase (R.J. Capon). Structure and biosynthesis of cyclopropane-containing sterols of marine origin (C. Djerassi and G.A. Doss). New natural products from terrestrial plants and marine organisms (V.U. Ahmad et al.). NMR in the elucidation of complex structures. Application to two novel heptanortriterpenoid derivatives from the stem bark of Entandrophragma utile ( Meliaceae ) (D.S. Rycroft). NMR of chalcogen nuclei and their application in natural products chemistry (H. Duddeck). Principles and applications of modern 2D NMR techniques in structure elucidation of complex natural products (Atta-ur-Rahman et al.). Rapid identification of trace amounts of indole alkaloids: Analysis of the aromatic pattern from the 1 H-NMR spectrum (J. Schripsema and R. Verpoorte). The Fusarium genus: A versatile biosynthetic engine (J.W. ApSimon et al.). Chemistry of self-inhibitors of fungal spore germination (T. Ueno et al.). Structural elucidation of some natural products (J.D. Connolly). Isolation and structural studies of constituents of Euphorbia fidjiana (R.C. Cambie et al.). Isolation and structure elucidation of new cytotoxic agents from Nerium oleander and chemical constituents of Azadirachta indica with reference to their biological activity (S. Siddiqui et al.). The chemistry of non-isoprenoid phenolic lipids (J.H.P. Tyman). "Bench-top" bioassays for the discovery of bioactive natural products: an update (J.L. McLaughlin et al.). Some advances in the research of corticoid hormones (R. Vlahov et al.). Bio-organic chemistry of ansamycin and mitomycin antibiotics (R.W. Rickards). Chromatographic and mass spectrometric methods for the analysis of the steryl esters of plants (R.P. Evershed and L.J. Goad). Tandem mass spectrometry ( FABMS/MS ) studies of peptides and proteins (K.L. Rinehart et al.). New results in phosphaheterocyclic chemistry and total synthesis of 25-oxa-25-phospha-vitamin D 3 - the first phosphorus analog of vitamin D 3 (R. Neidlein). Comparative studies of various Artemisia oils (P. Weyerstahl et al.). Peptide siderophores from bacteria (H. Budzikiewicz). Substrates and products of lipoxygenase catalysis (G.A. Veldink and J.F.G. Vliegenthart). Mechanistic and evolutionary aspects of vitamin B 12 biosynthesis (A.I. Scott). Subject Index.

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詳細情報

• NII書誌ID(NCID): BA11212150
• ISBN:
  • 0444888292
  • 044489165X
  • 0444820833
  • 0444822658
  • 044482815X
  • 0444501053
• LCCN: 88011188
• 出版国コード: ne
• タイトル言語コード: eng
• 本文言語コード: eng
• 出版地: Amsterdam ; Tokyo
• ページ数/冊数: v.
• 大きさ: 25 cm
• 分類:
  • LCC : QD415.A2
  • DC19 : 547.7
• 件名:
  • LCSH : Natural products
• 親書誌ID:
  • BA04899553