Synthesis and chemistry of agrochemicals

著者
書誌事項

Synthesis and chemistry of agrochemicals

Don R. Baker, Joseph G. Fenyes, William K. Moberg, Barrinton Cross, editor

(ACS symposium series, 355, 443, 504, 584, 686, 800, 948)

American Chemical Society, c1987-

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注記

"Developed from symposia sponsored by the Division of Agrochemicals, of the American Chemical Society"

3 : etitor , James J. Steffens

4 : editor , Gregory S. Basarab

5 : editors , Don R. Baker, Joseph G. Fenyes, Gregory S. Basarab, David A. Hunt

6 : editors , Don R. Baker, Joseph G. Fenyes, George P. Lahm, Thomas P. Selby, Thomas M. Stevenson

7 : editors , John W. Lyga, George Theodridis

Includes bibliographical references and indexes

内容説明・目次
巻冊次

[1] ISBN 9780841214347

内容説明

Chronicles current agricultural developments from initial concept to optimization of biological activity and safety, to field performance tests. Provides state-of-the-art developments in these areas of researched topics: herbicides, insecticides, fungicides, and other control methods. Offers a better understanding of the varied approaches to the discovery process in the agrochemical field.

目次

  • Overview of Agrochemical Development
  • 3-Isoxazolidinones and Related Compounds
  • Synthesis and Activity of Pyridazines
  • Properties of N-(Benzylideamino) Heterocycles
  • 2-Phenoxynicotinamides
  • 5-Aminofuran-3(2H)-ones
  • *a-Trichloroethylstyrene Oxides
  • o-(5-Thiono-2-imidazolin-2-yl)aryl Carboxylates
  • Benzylnitramines as Herbicides
  • *a-Cyano Vinylogous Ureas
  • 2-Aryl-1,2,4-triazin-3-ones
  • Aryl Herbicides
  • Chiral 3-Benzyloxytetrahydrofuran Grass Herbicides
  • Analogs of the Natural Herbicide Cyanobacterin
  • Peptides as Models for Selective Herbicides
  • Synthesis and Insecticidal Activity of Pyrethroids
  • Insecticidal Substituted Biphenylmethyl Oxime Ethers
  • Synthesis of Synthetic Pyrethroids
  • Heterobicyclic Oxime Carbamates
  • S-Cyanoalkyl Phosphorodithioates
  • Diphenylchloronitroethane Insecticides
  • Fluorinated Sulfonamides
  • Synthesis and Activity of Some Oxadiazolones
  • Synthetic Approaches to Milbemycin Analogs
  • Nonterpenoid S-Benzyl Thiolcarbamates
  • Compounds with Hydrazine- and Diazenecarboxamide Moieties
  • Biologically Active Organosilicon Compounds
  • Triazole Tertiary Alcohols
  • 2-Cyano Arylethyltriazoles as Agricultural Fungicides
  • Prochloraz and Its Analogues
  • Active Conformation of Azole Compounds
  • Laetisaric Acid
  • Carbamates, Thiolcarbamates & Cyanamides
  • Asymmetric Synthesis of Selected Insect Pheromones
  • Chemical Hybridizing Agents
  • Synthetic Approaches to Strigol and Its Analogs
  • Synthetic Studies of Strigol and Analogs
  • Biological Activity of Strigol, Its Precursors, and Its Analogs
巻冊次

2 ISBN 9780841218857

内容説明

This new volume explores the science of agricultural chemistry with studies covering the entire spectrum of herbicides, plant growth regulators, insecticides, insect pheromones, acaricides, and agricultural fungicides. Its two primary objectives are to provide chemists with integrated accounts of agrochemical discovery, synthesis, and development and to offer coherent updates on the current state of the discipline. The 46 chapters of this volume are divided into four sections covering sulfonylurea herbicides; other weed and plant control methods; control of insects, acarids, and nematodes; and control of fungi.
巻冊次

3 ISBN 9780841224735

内容説明

Covers the discovery, development, and optimization of new agrochemicals. Discusses new structures, new synthesis strategies, and structure-activity relationships of agrochemicals for plant control; insect, acarid, and nematode control; and fungal disease control. Also examines many of the toxicological problems encountered during development of new agrochemicals. Case histories describe the discovery and development of specific agrochemicals. Presents material and information that previously has only partially appeared in the patent literature.

目次

  • Progress in a Time of Change
  • 1,2,4-Triazolo[1,5-a]pyrimidine-2-sulfonanilide Herbicides: Influence of Alkyl, Haloalkyl, and Halogen Heterocyclic Substitution on In Vitro and In Vivo Biological Activity
  • 1,2,4-Triazolo[1,5-a]pyrimidine-2-sulfonanilide Herbicides: Influence of Alkoxy Heterocyclic Substitution on In Vitro and In Vivo Biological Activity and Soil Decomposition
  • N-(Substituted-2-fluorophenyl)- and N-(Substituted-2- trifluormethylphenyl)-1,2,4-triazolo -[1,5-a]pyrimidine-2-sulfonanilides: Synthesis and Herbicidal Activity
  • New Pyrazole Sulfonylureas: Synthesis and Herbicidal Activity
  • Synthesis and Quantitative Structure-Activity Relationships of Pyridylsulfonylurea Herbicides
  • Novel N-Substituted Imidazolinones: Synthesis and Herbicidal Activity
  • Discovery of a New Class of Herbicides: Sulfonyl Carboxamides
  • Phenyl-Substituted Five-Membered-Ring Heterocycles as Bleaching Herbicides
  • 7-Phenyl-1,2,4-triazolo[1,5-a]pyrimidines and Related Heterocycles: A New Family of Bleaching Herbicides
  • Diphenylpyridines: A New Class of Herbicides
  • Structure-Activity Relationships in 3-Alkyl- and 3-Aryl-5-isothiazolylureas: Pre- and Postemergence Herbicides with Two Possible Modes of Action
  • Design and Synthesis of 1-Aryl-4-substituted-1,4-dihydro-5H-tetrazol-5-ones: A Novel Pre- and Postemergence Class of Herbicides
  • Synthesis and Herbicidal Properties of Aryltriazolinones: A New Class of Pre- and Postemergence Herbicides
  • Novel Pryazole Phenyl Ether Herbidices
  • N-Substituted-2,6-(polyfluoromethyl)dihydropyridine-3,5- dicarboxylates: Synthesis and Herbicidal Activity
  • 5-Substituted-2,4-imidazolidinediones: Synthesis and Herbicidal Activity
  • Cyanoacrylate Inhibitors of Photosynthetic Electron Transport: Structural Requirements for Inhibitor Potency and Herbicidal Activity
  • Synthesis and Gametocidal Activity of 1-Aryl-5-(aminocarbonyl)-1H-pyrazole-4-carboxylic Acids
  • Discovery, Isolation, and Structure Elucidation of a Family of Structurally Unique, Fermentation-Derived Tetracyclic Macrolides
  • New Series of Milbemycin Macrolides (LL-F28249) with Endectocidal, Insecticidal, and Acaricidal Activity: Synthetic Modification and Biological Activity
  • Regio- and Stereoselective Synthesis of 13*b-Substituted-milbemycins, including the 13*b-Alkyl-milbemycins
  • Highly Efficacious Non-Ester Pyrethroid Insecticides with Low Toxicity to Fish
  • 1,4-Diaryl-1-cyclopropylbutanes: Highly Efficacious Insecticides with Low Fish Toxicity
  • Insecticidal Pyrroles: Discovery and Overview
  • Insecticidal Pyrroles: Arylpyrrolecarbonitriles Incorporating a Trifluoromethyl Group
  • Insecticidal Pyrroles: Synthesis of bis-(Trifluoromethyl) Pyrroles via Rearrangement of O-Vinyloximes
  • Insecticidal Dihydropyrazoles with Reduced Lipophilicity
  • N-Benzoyl-N-alkyl-2-aminothiazole Proinsecticides
  • Diphenylamines I: Synthesis and Structure-Activity Relationship Development of Novel N-(Substituted Phenyl)-N-alkyl-2-(trifluoromethyl)-4,6-dinitrobenzenamines Leading to a Potent Miticide(EL-462)
  • Diphenylamines II: Synthesis and Miticidal Activity of 2-Alkyl-4,6-dinitro- and 4-Alkyl-2,6-dinitrodiphenylamine Analogs and Derivatives
  • Synthesis and Reactivity of Cyclic Hydroxamic Acids: Resistance Factors in the Gramineae
  • Nematicidal Activity of 5-Substituted-2-S-(3,4,4-trifluoro-3-butenyl)-1,3,4-thiadiazoles
  • Fungicidal *b-Methoxyacrylates: From Natural Products to Novel Synthetic Agricultural Fungicides
  • Total Synthesis of Naturally Occurring 1,2-Dithiolo[4,3-b]pyrrolones and Related Compounds
  • Phenylpyrroles, a New Class of Agricultural Fungicides Related to the Natural Antibiotic Pyrrolnitrin
  • Synthesis of Fungicidal Phenylpyrroles
  • Design of Sterol Reductase Inhibitors: Insights into the Binding Conformation of Tertiary Amine Fungicides
  • Mechanism of the Antifungal Action of (S)-2-Amino-4-oxo-5-hydroxypentanoic Acid, RI-331: Inhibition of Homoserine Dehydrogenase in Saccharomyces cerevisiae
  • A Novel Class of Benzamide Fungicides
巻冊次

4 ISBN 9780841230910

内容説明

Presents the latest research in the discovery of new agrochemicals for the control of insects, acarids, weeds, and fungal diseases. Discusses structure-activity relationships in the design of novel agrochemicals and the use of bioisoteres and natural products as lead structures in discovery of new pest control agents. Presents examples of a variety of discovery rationales being used in biological systems. Examines the use of bioassays as indicators of chemical activity in biological systems. Details the synthetic methodology used in the laboratory preparation of a wide variety of biologically active agrochemicals.

目次

  • Bioassays in the Discovery Process of Agrochemicals
  • Bioisoterism in Agrochemicals
  • Synthesis and Herbicidal Activity of Sultamsulfonamides
  • Herbicidal Sulfonylamides
  • Synthesis of Imidazolinone Herbicides with Reduced Soil Persistence: Derivatives of 5-Formyl-2-imidazolin-2-yl-nicotinic Acids
  • Cyclic Imidate Derivatives of 5-Amino-2,6-bis(polyfluoroalkyl)-pyridine-3-carboxylates: Synthesis and Herbicidal Activity
  • Thiazolo[4,5-b]pyridine-3(2H)-acetic Acid Derivatives: Synthesis and Herbicidal Activity
  • Herbicidal 1-(2,4-Dihale-5-[henoxyphenyl)-4-difluor omethyl-4,5-dihydro-3-methyl-1,2,4-triazolin-5(1H)-one Derivatives: Synthesis and Structure-Activity Relationships
  • Tetrahydropyridazine Derivatives: Synthesis, Reactivity, and Herbicidal Activity of Heterocycle Fused Tetrahydropyridazines
  • 3-Aryl-4-substituted-5-(halo)alkylisoxazoles: Design, Synthesis, and Herbicidal Activity of a Unique Class of Pre- and Postemergent Herbicides
  • 6-Aryloxy-1H-benzotriazoles: Synthesis and Herbicidal Activity
  • Aryloxyindolin-2(3H)-ones: Synthesis and Herbicidal Activity
  • 5-Aryloxybenzisoxazole Esters: Synthesis and Herbicidal Activity
  • Phytoene Desaturase: A Model for the Optimization of Inhibitors
  • Aryl-Substituted Quinoxalines and Related Heteroarenes as Novel Herbicides Prepared via Palladium-Catalyzed Cross-Coupling Methods
  • Novel Pyrimidine Bleaching Herbicides: Synthesis and Herbicidal Activity
  • Oxazine Ether Herbicides: Novel Grass-Selectivie Compounds
  • Herbicidally Active Sulfamoyl Nucleosides: Isolation and Synthesis
  • Arloxy- and Pyridyloxylphenylcyclohexanediene Grass Herbicides: Synthesis and Herbical Activity
  • Insectical 1-Cyclopropyl01,4-diarylbutenes and 1,4-Diarylbutanes
  • Novel 1-Cyclopropyl-1-(4-substitued phenyl)-4-cyano-(4-fluoro-3-phenoxylphenyl)butane Insecticides
  • (-)-(4-Fluoro-3-phenoxyl)methyl 2-Cyclopropyl-2-(4-trifluoromethoxylphenyl)ethyl Ether, a Highly Efficacious Nonester Pyethroid Insecticide and Acaricide: Synthesis and Enzymatic Resolution
  • INsecticidal Dibenzoexecinopyrazoline Carboxamides
  • 1,5-Diphenylpyrazoline-3-carboxanilides: A New Class of Insecticides
  • 1-Arylpyrazoline-3-carboxanilides: A New class of Insecticides
  • Insecticidal 2-Aryl-3-trifluoromethylsulfonylpyrroles
  • Monoterpenoids and Their Synthetic Derivatives as Leads for New Insect-Control Agents
  • Fungical *b-Methoxylacrylates:N-linked Pyrroles
  • Phenoxyphenyl Alloxylmineacetamides: New Broad-Spectrum Fungicides
  • Retrospective Quantitative Structure-Activity Relationship (QSAR) Analysis of Tetrazolo- and Triazolo-quinolines, a Series of Rice Blast Control Agents
  • Synthesis and Fungicidal Activity of 2-Cyanoimidazoles
  • Novel and Selective Quinazolinyl Arylureas: Synthesis and Fungicidal Activity
  • Oxime Fungicides:Highly Active Broad-Spectrum Protectants
  • 2-Cyanoarylethyltriazoles as Agricultural Fungicides: Discovery of Fenbuconazole
  • Synthesis and Biological Properties of Fenbuconazole Metabolites
  • Novel Class of Pyridyl Fungicides
  • Synthesis and Fungicidal Activity of N-Phenylpyridinamines
  • Antimicrobial Properties of Natural Volatile Compounds
  • Nitrosation of Tobacco Alkaloids During Storage Reduced by Antimicrobial (E)-2-Hexenal Vapor
巻冊次

5 ISBN 9780841235465

内容説明

Collecting up-to-date research, this book covers a wide range of agrochemicals for controlling insects, mites, weeds, and plant and fungal diseases. It discusses structural-activity relationships in the design of new pest control agents and describes a variety of approaches to developing new agrochemicals. It provides an overview of the role of biotechnology in pest control, while detailing synthetic methodology used in preparing biologically active agrochemicals. It also covers natural chemicals with important agrochemical potential.
巻冊次

6 ISBN 9780841237834

内容説明

This 30-chapter volume is a complete reference book that includes current updates and trends in the field of agrochemicals. Topics in the book include herbicides in agriculture, control of insects and acrids in agriculture, and control of fungal disease in agriculture.
巻冊次

7 ISBN 9780841239678

内容説明

This book will be a continuation in the series of Synthesis and Chemistry of Agrochemicals. The focus of this volume is the translation of pesticidal activity from the lab to the greenhouse to the field. The book will cover the chemistry, ADMET and biochemistry research lending a better understanding of the issues involved with loss in activity going from lab assays to greenhouse and field. The second topic covered is synthesis of agrochemicals. This topic will address the good ideas that never made it to products, chemistry work done in the field of agriculture that was based on a good hypothesis yet never made it to a product. The chapters will cover insecticide, herbicide, fungicide and specialty products.

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