Polymer-polymer miscibility
著者
書誌事項
Polymer-polymer miscibility
Academic Press, 1979
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
Polymer-Polymer Miscibility discusses miscibility of polymeric mixtures. This book explains the theoretical and practical aspects of polymer miscibility, which has become a considerable area of research in many academic and industrial laboratories. Comprised of seven chapters, this book starts with an overview of the physical nature of the variations of the basic polymer structure. This monograph then discusses the two cases of miscible polymer blends, namely, poly(vinyl chloride) (PVC)-butadiene/acrylonitrile copolymer (NBR) and polystyrene-poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) blends. This text explores the useful and unique properties of blends of poly(vinyl chloride) and butadiene/acrylonitrile copolymer rubber. Other chapters discuss the thermodynamic theories for the phase separation of block copolymers. The reader is also introduced to other variations of chemical structure, which can result in the permanent attachment of polymers to each other through block and graft copolymers. This text also explores the feasibility of covalent bonding of polymer components. This book is intended for chemical engineers and materials scientists.
目次
PrefaceChapter 1 Introduction 1.1 Two-Component Systems: Definitions 1.2 Historical Background with Commercial Examples ReferencesChapter 2 Thermodynamics of Polymer-Polymer Miscibility 2.1 General Thermodynamic Principles 2.2 Phase Separation Phenomena 2.3 Hildebrand Approach: The Solubility Parameter 2.4 Flory-Huggins Approach: The Lattice Theory 2.5 Equation-of-State Approach 2.6 Thermodynamics of Block Copolymer Systems ReferencesChapter 3 Methods for Determining Polymer-Polymer Miscibility 3.1 Criteria for Establishing Miscibility 3.2 Glass Transition Temperature 3.3 Microscopy 3.4 Scattering Methods 3.5 Ternary-Solution Methods 3.6 Miscellaneous ReferencesChapter 4 Methods of Enhancing Miscibility 4.1 Minor Modifications of Structure 4.2 Block and Graft Copolymer Formation 4.3 Interpenetrating Network Formation 4.4 Cross-Linking 4.5 Introduction of Interacting Groups 4.6 Miscellaneous ReferencesChapter 5 Comprehensive Survey of Miscible Polymer Systems 5.1 Criteria for Selection 5.2 Referenced Listing 5.3 Discussion ReferencesChapter 6 Properties of Miscible Polymer Systems 6.1 Thermal and Thermomechanical 6.2 Mechanical 6.3 Electrical 6.4 Rheological and Viscoelastic 6.5 Transport 6.6 Crystallization 6.7 Degradation ReferencesChapter 7 Utilization of Miscible Polymers 7.1 Industrial Examples 7.2 Mechanical Compatibility versus Miscibility in Polymer Blends ReferencesAppendix 1 NomenclatureAppendix 2 Abbreviations for Polymer NamesIndex
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