Phase transfer catalysis
著者
書誌事項
Phase transfer catalysis
VCH, c1993
3rd, rev. and enl. ed
- : us
- : gw
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
The third revised and enlarged edition of this book covers the subject of phase transfer catalysis. It begins with a discussion of the underlying physicochemical principles, and extends through applications into various fields of synthesis. Aimed at the practising chemist, it provides typical experimental procedures for more frequently used applications of phase transfer catalysis.
目次
- Ion pairs and ion pair extraction
- introduction - the nature of phase transfer catalysis
- ion pairs in organic media
- extraction of ion pairs from aqueous solution
- crown ethers, cryptates, and other chelating agents as extractants
- solid-liquid anion exchange
- mechanism of phase transfer catalysis
- mechanistic investigations
- empirical catalyst evaluations
- unusual and polymer supported catalysts
- practical applications of phase transfer catalysis
- general experimental procedures
- formation of halides
- preparation of nitriles
- ester formation
- miscellaneous displacements
- thiols and sulfides
- preparation of ethers
- N-alkylations
- C-alkylation of activated CH-bonds
- alkylation of ambident anions
- isomerizations and H/D exchange
- additons across multiple CC-bonds
- addition to C=O and C=N bonds
- beta-eliminations
- hydrolysis reactions
- generation and conversion of phosphonium and sulfonium ylides
- nucleophilic aromatic substitution
- miscellaneous reactions
- organometallic PTC applications
- alpha-eliminations
- reduction reactions.
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